Grignard Addition to Aldonitrones. Stereochemical Aspects and Application to the Synthesis of C2-Symmetric Diamino Alcohols and Diamino Diols
A new example of the stereoselective installation of the amino group at a saturated carbon center via organometallic addition of chiral aldehydes to nitrones is illustrated by the synthesis of 1,3-diamino propanol 1 and 1,4-diamino butandiol 2 units. Three diamino alcohol 1 stereotriads were obtaine...
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| Veröffentlicht in: | Journal of organic chemistry 1998-12, Vol.63 (25), p.9252-9264 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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