Synthesis, Structure, and Reactivity of [RuCl(PP)L]PF6 (PP = (PPh3)2, Ph2P(CH2)4PPh2; L = P(py)3, PPh(py)2, py = 2-pyridyl). The “Missing” P,N,N‘-Coordination Mode for 2-Pyridylphosphines

The complexes [RuCl(PPh3)2(P,N,N‘-PPh3- x (py) x )]PF6 (x = 2, 1b; 3, 1c; py = 2-pyridyl) were isolated from the reaction of RuCl2(PPh3)3 with 1 equiv of PPh3- x (py) x and NH4PF6 in acetone. Crystals of 1b (C52H43ClF6N2P4Ru) are monoclinic, a = 17.795(2), b = 11.375(4), and c = 23.343(2) Å, β = 97....

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Veröffentlicht in:	Inorganic chemistry 1997-12, Vol.36 (25), p.5809-5817
Hauptverfasser:	Schutte, Richard P, Rettig, Steven J, Joshi, Ajey M, James, Brian R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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