Reversible Isomerization of a Diphosphine Ligand about a Triosmium Cluster:  Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3(CO)10[(Z)-Ph2PCHCHPPh2]

Substitution of the MeCN ligands in the activated cluster Os3(CO)10(MeCN)2 (1) by the unsaturated diphosphine ligand (Z)-Ph2PCHCHPPh2 proceeds rapidly at room temperature to furnish the ligand-bridged cluster 1,2-Os3(CO)10[(Z)-Ph2PCHCHPPh2] (2b). Heating 2b leads to the formation of the thermodyna...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 2005-10, Vol.24 (22), p.5431-5439
Hauptverfasser:	Watson, William H, Wu, Guanmin, Richmond, Michael G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!