Synthetic, Structural, Spectroscopic, and Theoretical Studies of Structural Isomers of the Cluster Pt3(μ-PPh2)3Ph(PPh3)2. A Unique Example of Core Isomerism in Phosphine Phosphido-Rich Clusters

Two isomers of the phosphido-bridged platinum cluster Pt3(μ-PPh2)3Ph(PPh3)2 (2 and 3) have been isolated, and their structures have been solved by single-crystal X-ray diffraction. Compound 2 crystallizes in the orthorhombic space group Cmc21 with a = 22.192(10) Å, b = 17.650(9) Å, c = 18.182(8) Å,...

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Veröffentlicht in:	Inorganic chemistry 1996-02, Vol.35 (5), p.1223-1234
Hauptverfasser:	Bender, Robert, Braunstein, Pierre, Dedieu, Alain, Ellis, Paul D, Huggins, Beth, Harvey, Pierre D, Sappa, Enrico, Tiripicchio, Antonio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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