Formation of a Titanium Complex with a TiCHAl2 Structural Unit from LTiMe3 and Trimethylaluminum

The reaction of LTiCl3 (1) (L = HC(CMeN(2,6-iPr2C6H3))2, nacnac) with MeLi·(Et2O)0.14 in toluene afforded the stable Ti(IV) alkyl complex LTiMe3 (1). Reaction of 1 with 2 equiv of AlMe3 in toluene resulted in the formation of LTi(Me)CH(Al2Me5) (2) in high yield. Compounds 1 and 2 were characterized...

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Veröffentlicht in:	Organometallics 2008-06, Vol.27 (11), p.2544-2548
Hauptverfasser:	Nikiforov, Grigory B, Roesky, Herbert W, Heisen, Burkhard C, Oswald, Rainer B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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