New Configurationally Stable Chiral Building Blocks for Polynuclear Coordination Compounds:  Ru(chiragen[X])Cl2

The two enantiomers (Δ and Λ) of Ru(chiragen[X])Cl2, where “chiragen” is a tetradentate ligand with a chiral bridging unit between two bipyridine moieties, have been prepared in high yields. X is m-xylyl (m-xyl); other bridging groups (e.g., −(CH2)5− or −(CH2)6−) behave similarly. This complex can b...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-08, Vol.118 (34), p.7989-7994
Hauptverfasser:	Mürner, Hansruedi, Belser, Peter, von Zelewsky, Alex
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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