Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN
The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2- C5H4N)(CH2NSiMe3)2] undergoes a [2+2] cycloaddition reaction with ButCP to form the mononuclear product [Ti{N(But)PC(But)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti2{μ-η2-NC(Me)NBut...
Gespeichert in:
| Veröffentlicht in: | Organometallics 2000-08, Vol.19 (16), p.3205-3210 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3210 |
|---|---|
| container_issue | 16 |
| container_start_page | 3205 |
| container_title | Organometallics |
| container_volume | 19 |
| creator | Pugh, Stephen M Trösch, Dominique J. M Wilson, D. James Bashall, Alan Cloke, F. Geoffrey N Gade, Lutz H Hitchcock, Peter B McPartlin, Mary Nixon, John F Mountford, Philip |
| description | The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2- C5H4N)(CH2NSiMe3)2] undergoes a [2+2] cycloaddition reaction with ButCP to form the mononuclear product [Ti{N(But)PC(But)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti2{μ-η2-NC(Me)NBut}2(L)2] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4). |
| doi_str_mv | 10.1021/om000264u |
| format | Article |
| fullrecord | <record><control><sourceid>istex_acs_j</sourceid><recordid>TN_cdi_istex_primary_ark_67375_TPS_M3C21Z0Q_8</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_M3C21Z0Q_8</sourcerecordid><originalsourceid>FETCH-LOGICAL-a688-e475b78c13769ca10f9c4ebc42d03687a2a7b70d4f7e0b0c90e17747b322ec983</originalsourceid><addsrcrecordid>eNo90M9LwzAUB_AgCs7pwf8gF6E9VF-StmmPGtQNtjpdT4qENE1Z5tqO_kCH-L_bMfH03uHDl_e-CF0SuCZAyU1dAgAN_f4IjUhAwQvBJ8doBJSHHmeMnaKztl0PKOSMjtBa7PSmVnluO1tX-MUovV9aXBe4Wxmc2k5Vti_xtLS5wW-pdZK7vnO_50Y41BPBxE9cR0xosrRzw1z642x37jv-tN0KD1AssKpyPOjkHJ0UatOai785RunDfSom3uzpcSpuZ54Ko8gzPg8yHmnCeBhrRaCItW8y7dMcWBhxRRXPOOR-wQ1koGMwhHOfZ4xSo-OIjZF3iLVtZ77ktrGlanZSNR9yeJkHMl0s5ZwJSl7hWe791cEr3cp13TfVcJwkIPd9yv8-2S8d0WOT</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN</title><source>American Chemical Society Journals</source><creator>Pugh, Stephen M ; Trösch, Dominique J. M ; Wilson, D. James ; Bashall, Alan ; Cloke, F. Geoffrey N ; Gade, Lutz H ; Hitchcock, Peter B ; McPartlin, Mary ; Nixon, John F ; Mountford, Philip</creator><creatorcontrib>Pugh, Stephen M ; Trösch, Dominique J. M ; Wilson, D. James ; Bashall, Alan ; Cloke, F. Geoffrey N ; Gade, Lutz H ; Hitchcock, Peter B ; McPartlin, Mary ; Nixon, John F ; Mountford, Philip</creatorcontrib><description>The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2- C5H4N)(CH2NSiMe3)2] undergoes a [2+2] cycloaddition reaction with ButCP to form the mononuclear product [Ti{N(But)PC(But)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti2{μ-η2-NC(Me)NBut}2(L)2] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4).</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om000264u</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 2000-08, Vol.19 (16), p.3205-3210</ispartof><rights>Copyright © 2000 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om000264u$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om000264u$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Pugh, Stephen M</creatorcontrib><creatorcontrib>Trösch, Dominique J. M</creatorcontrib><creatorcontrib>Wilson, D. James</creatorcontrib><creatorcontrib>Bashall, Alan</creatorcontrib><creatorcontrib>Cloke, F. Geoffrey N</creatorcontrib><creatorcontrib>Gade, Lutz H</creatorcontrib><creatorcontrib>Hitchcock, Peter B</creatorcontrib><creatorcontrib>McPartlin, Mary</creatorcontrib><creatorcontrib>Nixon, John F</creatorcontrib><creatorcontrib>Mountford, Philip</creatorcontrib><title>Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2- C5H4N)(CH2NSiMe3)2] undergoes a [2+2] cycloaddition reaction with ButCP to form the mononuclear product [Ti{N(But)PC(But)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti2{μ-η2-NC(Me)NBut}2(L)2] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4).</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNo90M9LwzAUB_AgCs7pwf8gF6E9VF-StmmPGtQNtjpdT4qENE1Z5tqO_kCH-L_bMfH03uHDl_e-CF0SuCZAyU1dAgAN_f4IjUhAwQvBJ8doBJSHHmeMnaKztl0PKOSMjtBa7PSmVnluO1tX-MUovV9aXBe4Wxmc2k5Vti_xtLS5wW-pdZK7vnO_50Y41BPBxE9cR0xosrRzw1z642x37jv-tN0KD1AssKpyPOjkHJ0UatOai785RunDfSom3uzpcSpuZ54Ko8gzPg8yHmnCeBhrRaCItW8y7dMcWBhxRRXPOOR-wQ1koGMwhHOfZ4xSo-OIjZF3iLVtZ77ktrGlanZSNR9yeJkHMl0s5ZwJSl7hWe791cEr3cp13TfVcJwkIPd9yv8-2S8d0WOT</recordid><startdate>20000807</startdate><enddate>20000807</enddate><creator>Pugh, Stephen M</creator><creator>Trösch, Dominique J. M</creator><creator>Wilson, D. James</creator><creator>Bashall, Alan</creator><creator>Cloke, F. Geoffrey N</creator><creator>Gade, Lutz H</creator><creator>Hitchcock, Peter B</creator><creator>McPartlin, Mary</creator><creator>Nixon, John F</creator><creator>Mountford, Philip</creator><general>American Chemical Society</general><scope>BSCLL</scope></search><sort><creationdate>20000807</creationdate><title>Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN</title><author>Pugh, Stephen M ; Trösch, Dominique J. M ; Wilson, D. James ; Bashall, Alan ; Cloke, F. Geoffrey N ; Gade, Lutz H ; Hitchcock, Peter B ; McPartlin, Mary ; Nixon, John F ; Mountford, Philip</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a688-e475b78c13769ca10f9c4ebc42d03687a2a7b70d4f7e0b0c90e17747b322ec983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pugh, Stephen M</creatorcontrib><creatorcontrib>Trösch, Dominique J. M</creatorcontrib><creatorcontrib>Wilson, D. James</creatorcontrib><creatorcontrib>Bashall, Alan</creatorcontrib><creatorcontrib>Cloke, F. Geoffrey N</creatorcontrib><creatorcontrib>Gade, Lutz H</creatorcontrib><creatorcontrib>Hitchcock, Peter B</creatorcontrib><creatorcontrib>McPartlin, Mary</creatorcontrib><creatorcontrib>Nixon, John F</creatorcontrib><creatorcontrib>Mountford, Philip</creatorcontrib><collection>Istex</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pugh, Stephen M</au><au>Trösch, Dominique J. M</au><au>Wilson, D. James</au><au>Bashall, Alan</au><au>Cloke, F. Geoffrey N</au><au>Gade, Lutz H</au><au>Hitchcock, Peter B</au><au>McPartlin, Mary</au><au>Nixon, John F</au><au>Mountford, Philip</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>2000-08-07</date><risdate>2000</risdate><volume>19</volume><issue>16</issue><spage>3205</spage><epage>3210</epage><pages>3205-3210</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2- C5H4N)(CH2NSiMe3)2] undergoes a [2+2] cycloaddition reaction with ButCP to form the mononuclear product [Ti{N(But)PC(But)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti2{μ-η2-NC(Me)NBut}2(L)2] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4).</abstract><pub>American Chemical Society</pub><doi>10.1021/om000264u</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 2000-08, Vol.19 (16), p.3205-3210 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_istex_primary_ark_67375_TPS_M3C21Z0Q_8 |
| source | American Chemical Society Journals |
| title | Cycloaddition Reactions of the Titanium Imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)2}(py)] with ButCP and MeCN |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T05%3A19%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_acs_j&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cycloaddition%20Reactions%20of%20the%20Titanium%20Imide%20%5BTi(NBut)%7BMeC(2-C5H4N)(CH2NSiMe3)2%7D(py)%5D%20with%20ButCP%20and%20MeCN&rft.jtitle=Organometallics&rft.au=Pugh,%20Stephen%20M&rft.date=2000-08-07&rft.volume=19&rft.issue=16&rft.spage=3205&rft.epage=3210&rft.pages=3205-3210&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om000264u&rft_dat=%3Cistex_acs_j%3Eark_67375_TPS_M3C21Z0Q_8%3C/istex_acs_j%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |