Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr

Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr

The monomeric bis(indenyl) complex [1,3-(C3H7)2C9H5)]2Cr is high spin from 20 K to room temperature. The isopropyl groups block the dimerization that occurs with the unsubstituted (C9H7)2Cr complex but do not affect its spin state.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 1999-08, Vol.18 (18), p.3561-3562
Hauptverfasser: Overby, Jason S, Hanusa, Timothy P, Sellers, Scott P, Yee, Gordon T
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 3562
container_issue 18
container_start_page 3561
container_title Organometallics
container_volume 18
creator Overby, Jason S
Hanusa, Timothy P
Sellers, Scott P
Yee, Gordon T
description The monomeric bis(indenyl) complex [1,3-(C3H7)2C9H5)]2Cr is high spin from 20 K to room temperature. The isopropyl groups block the dimerization that occurs with the unsubstituted (C9H7)2Cr complex but do not affect its spin state.
doi_str_mv 10.1021/om990433e
format Article
fullrecord <record><control><sourceid>acs_istex</sourceid><recordid>TN_cdi_istex_primary_ark_67375_TPS_LRC9KD2W_3</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b954673693</sourcerecordid><originalsourceid>FETCH-LOGICAL-a136t-9e5dd1ba0adb77ef945dbc1119aa5a5564af8ab5d72a9b3387528fd3b08808c03</originalsourceid><addsrcrecordid>eNo9kF1LwzAYhYMoOKcX_oPcCBssmo-maS4lfrQ4UOzUC5Hwtk1d5tqOtoPNX-9k4tW5eTic8yB0zuglo5xdNZXWNBDCHaABk5ySkAbsEA0oVyFRQohjdNJ1C0ppqAQfoNe0d63PcdpD5pf-G3rf1LgpMeDYf85JuvI1NvO2qfy6GiXJGCd14ertEpumWi3dZoLf2USQkRGxGnOjY_nBTXuKjkpYdu7sL4fo5e52ZmIyfbxPzPWUABNhT7STRcEyoFBkSrlSB7LIcsaYBpAgZRhAGUEmC8VBZ0JESvKoLERGo4hGORVDRPa9vuvdxq5aX0G7tdB-2d0_Je3sKbXTZ6MfbvibFTv-Ys9D3tlFs27r3TrLqP2VZ__liR9j2l3u</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr</title><source>American Chemical Society Journals</source><creator>Overby, Jason S ; Hanusa, Timothy P ; Sellers, Scott P ; Yee, Gordon T</creator><creatorcontrib>Overby, Jason S ; Hanusa, Timothy P ; Sellers, Scott P ; Yee, Gordon T</creatorcontrib><description>The monomeric bis(indenyl) complex [1,3-(C3H7)2C9H5)]2Cr is high spin from 20 K to room temperature. The isopropyl groups block the dimerization that occurs with the unsubstituted (C9H7)2Cr complex but do not affect its spin state.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om990433e</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 1999-08, Vol.18 (18), p.3561-3562</ispartof><rights>Copyright © 1999 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om990433e$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om990433e$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Overby, Jason S</creatorcontrib><creatorcontrib>Hanusa, Timothy P</creatorcontrib><creatorcontrib>Sellers, Scott P</creatorcontrib><creatorcontrib>Yee, Gordon T</creatorcontrib><title>Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The monomeric bis(indenyl) complex [1,3-(C3H7)2C9H5)]2Cr is high spin from 20 K to room temperature. The isopropyl groups block the dimerization that occurs with the unsubstituted (C9H7)2Cr complex but do not affect its spin state.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNo9kF1LwzAYhYMoOKcX_oPcCBssmo-maS4lfrQ4UOzUC5Hwtk1d5tqOtoPNX-9k4tW5eTic8yB0zuglo5xdNZXWNBDCHaABk5ySkAbsEA0oVyFRQohjdNJ1C0ppqAQfoNe0d63PcdpD5pf-G3rf1LgpMeDYf85JuvI1NvO2qfy6GiXJGCd14ertEpumWi3dZoLf2USQkRGxGnOjY_nBTXuKjkpYdu7sL4fo5e52ZmIyfbxPzPWUABNhT7STRcEyoFBkSrlSB7LIcsaYBpAgZRhAGUEmC8VBZ0JESvKoLERGo4hGORVDRPa9vuvdxq5aX0G7tdB-2d0_Je3sKbXTZ6MfbvibFTv-Ys9D3tlFs27r3TrLqP2VZ__liR9j2l3u</recordid><startdate>19990830</startdate><enddate>19990830</enddate><creator>Overby, Jason S</creator><creator>Hanusa, Timothy P</creator><creator>Sellers, Scott P</creator><creator>Yee, Gordon T</creator><general>American Chemical Society</general><scope>BSCLL</scope></search><sort><creationdate>19990830</creationdate><title>Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr</title><author>Overby, Jason S ; Hanusa, Timothy P ; Sellers, Scott P ; Yee, Gordon T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a136t-9e5dd1ba0adb77ef945dbc1119aa5a5564af8ab5d72a9b3387528fd3b08808c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Overby, Jason S</creatorcontrib><creatorcontrib>Hanusa, Timothy P</creatorcontrib><creatorcontrib>Sellers, Scott P</creatorcontrib><creatorcontrib>Yee, Gordon T</creatorcontrib><collection>Istex</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Overby, Jason S</au><au>Hanusa, Timothy P</au><au>Sellers, Scott P</au><au>Yee, Gordon T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1999-08-30</date><risdate>1999</risdate><volume>18</volume><issue>18</issue><spage>3561</spage><epage>3562</epage><pages>3561-3562</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The monomeric bis(indenyl) complex [1,3-(C3H7)2C9H5)]2Cr is high spin from 20 K to room temperature. The isopropyl groups block the dimerization that occurs with the unsubstituted (C9H7)2Cr complex but do not affect its spin state.</abstract><pub>American Chemical Society</pub><doi>10.1021/om990433e</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0276-7333
ispartof Organometallics, 1999-08, Vol.18 (18), p.3561-3562
issn 0276-7333
1520-6041
language eng
recordid cdi_istex_primary_ark_67375_TPS_LRC9KD2W_3
source American Chemical Society Journals
title Steric Stabilization of a High-Spin Chromium(II) Indenyl Complex, [1,3-(C3H7)2C9H5]2Cr
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T00%3A37%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_istex&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Steric%20Stabilization%20of%20a%20High-Spin%20Chromium(II)%20Indenyl%20Complex,%20%5B1,3-(C3H7)2C9H5%5D2Cr&rft.jtitle=Organometallics&rft.au=Overby,%20Jason%20S&rft.date=1999-08-30&rft.volume=18&rft.issue=18&rft.spage=3561&rft.epage=3562&rft.pages=3561-3562&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om990433e&rft_dat=%3Cacs_istex%3Eb954673693%3C/acs_istex%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true