Synthesis and Structure of a Novel Lithium Gallosiloxane Containing a Ga4Si4O8 Macrocycle Analogous to the S8R Building Unit of Zeolites

The reaction of LiGaMe4 with diphenysilanediol in THF at 50 °C leads to the formation of the title gallosiloxane Li2(Li(THF)2)2[Ph2SiO2GaMe2]2[Ph2SiO2GaMe(OH)]2·2THF (1), which is made up of a central tetraanionic Ga4Si4O8 16-membered macrocyclic core. The cavity that is created by this tetraanionic...

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Veröffentlicht in:	Organometallics 2001-06, Vol.20 (12), p.2639-2642
Hauptverfasser:	Murugavel, Ramaswamy, Walawalkar, Mrinalini G, Prabusankar, Ganesan, Davis, Paul
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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