Mechanistic Studies on the Aryl−Aryl Interchange Reaction of ArPdL2I (L = Triarylphosphine) Complexes

The aryl−aryl interchange reaction of ArPdL2I complex 1m was found to follow pseudo-first-order kinetics. A marked inhibition in the presence of excess phosphine and/or excess iodide was observed, suggesting that a dissociative pathway was involved, contrary to the analogous alkyl−aryl interchange r...

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Veröffentlicht in:	Journal of the American Chemical Society 1997-12, Vol.119 (51), p.12441-12453
Hauptverfasser:	Goodson, Felix E, Wallow, Thomas I, Novak, Bruce M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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