Steric Consequences on the Conformation of Medium-Sized Rings:  Solution NMR, Solid-State Crystallographic, ab Initio Molecular Orbital Calculations, and Molecular Mechanics Studies on Substituted Eight-Membered Organosilicon Ring Systems1

The conformation of the eight-membered membered 12H-dibenzo[d,g][1,3,2]dioxasilocin ring system was investigated both in the solid-state by X-ray crystallography and in solution by NOE experiments. Ab initio Hartree−Fock calculations were performed to locate all stationary points for the unsubstitut...

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Veröffentlicht in:	Journal of the American Chemical Society 1997-09, Vol.119 (35), p.8313-8323
Hauptverfasser:	Burke, Lilibeth P, DeBellis, Anthony D, Fuhrer, Herman, Meier, Hansrudolf, Pastor, Stephen D, Rihs, Grety, Rist, Guenther, Rodebaugh, Ronald K, Shum, Sai P
Format:	Artikel
Sprache:	eng ; jpn
Online-Zugang:	Volltext
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