Experimental and Theoretical Evidence of an SN2-Type Mechanism for Dissociation of B−N Coordination Bonds in 2,6-Bis((dimethylamino)methyl)phenylborane Derivatives1

To distinguish between dissociation of a B−N coordination bond by SN1- and SN2-type mechanisms, two series of 1,3,2-dioxaborolanes (boronates) and BEt2 (borane) complexes carrying a 2,6-bis((dimethylamino)methyl)phenyl group as a third substituent were synthesized by the reaction of the correspondin...

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Veröffentlicht in:	Organometallics 1998-09, Vol.17 (19), p.4155-4163
Hauptverfasser:	Toyota, Shinji, Futawaka, Tadahiro, Asakura, Mitsuhiro, Ikeda, Hiroshi, Ōki, Michinori
Format:	Artikel
Sprache:	eng ; jpn
Online-Zugang:	Volltext
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