Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane

The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be a...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	The journal of physical chemistry. B 2001-05, Vol.105 (18), p.3937-3941
Hauptverfasser:	Fenelonov, Vladimir B, Mel'gunov, Maxim S, Mishakov, Ilya V, Richards, Ryan M, Chesnokov, Vladimir V, Volodin, Alexander M, Klabunde, Kenneth J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	3941
container_issue	18
container_start_page	3937
container_title	The journal of physical chemistry. B
container_volume	105
creator	Fenelonov, Vladimir B Mel'gunov, Maxim S Mishakov, Ilya V Richards, Ryan M Chesnokov, Vladimir V Volodin, Alexander M Klabunde, Kenneth J
description	The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be an active catalyst for the dehydrochlorination reaction, so the rate of 1-chlorobutane conversion grows significantly with time. Changes in the MgO texture during the topochemical reaction are discussed and their effect on the catalytic activity is estimated.
doi_str_mv	10.1021/jp0039969
format	Article
fullrecord	<record><control><sourceid>acs_istex</sourceid><recordid>TN_cdi_istex_primary_ark_67375_TPS_GLF9WN0C_H</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a236613683</sourcerecordid><originalsourceid>FETCH-LOGICAL-a221t-8ff29e45655fce6a462c480c35e36c60ae034f9274a98edbd8e34871ecf403d93</originalsourceid><addsrcrecordid>eNo9kMtOwzAURCMEEqWw4A-8YRnwI3GSZRXRh1RaBEEsrVvHaVxSp7JdaL6A3yaliMXojjRHo6sJgluC7wmm5GGzw5hlGc_OggGJKQ57Jed_nhPML4Mr5zYY05imfBB85zWYtXJIG1Sog99bhcCUKAcPTee1RCPp9af2HWortADTStu5Pmu0UehpvUTl3mqzRjPvUGHBuKq1W_C6Nci3PZA39Njta4VeFMjf4Ev7GpEwr5vWtqu9B6Oug4sKGqdu_u4weBs_Fvk0nC8ns3w0D4FS4sO0qmimopjHcSUVh4hTGaVYslgxLjkGhVlUZTSJIEtVuSpTxaI0IUpWEWZlxoZBeOrVzquD2Fm9BdsJsB-CJyyJRfH8Kibzcfa-wLmY9vzdiQfpxKbdW9N_JwgWx7XF_9rsBwa3cok</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane</title><source>ACS Publications</source><creator>Fenelonov, Vladimir B ; Mel'gunov, Maxim S ; Mishakov, Ilya V ; Richards, Ryan M ; Chesnokov, Vladimir V ; Volodin, Alexander M ; Klabunde, Kenneth J</creator><creatorcontrib>Fenelonov, Vladimir B ; Mel'gunov, Maxim S ; Mishakov, Ilya V ; Richards, Ryan M ; Chesnokov, Vladimir V ; Volodin, Alexander M ; Klabunde, Kenneth J</creatorcontrib><description>The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be an active catalyst for the dehydrochlorination reaction, so the rate of 1-chlorobutane conversion grows significantly with time. Changes in the MgO texture during the topochemical reaction are discussed and their effect on the catalytic activity is estimated.</description><identifier>ISSN: 1520-6106</identifier><identifier>EISSN: 1520-5207</identifier><identifier>DOI: 10.1021/jp0039969</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>The journal of physical chemistry. B, 2001-05, Vol.105 (18), p.3937-3941</ispartof><rights>Copyright © 2001 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp0039969$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp0039969$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,27074,27922,27923,56736,56786</link.rule.ids></links><search><creatorcontrib>Fenelonov, Vladimir B</creatorcontrib><creatorcontrib>Mel'gunov, Maxim S</creatorcontrib><creatorcontrib>Mishakov, Ilya V</creatorcontrib><creatorcontrib>Richards, Ryan M</creatorcontrib><creatorcontrib>Chesnokov, Vladimir V</creatorcontrib><creatorcontrib>Volodin, Alexander M</creatorcontrib><creatorcontrib>Klabunde, Kenneth J</creatorcontrib><title>Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane</title><title>The journal of physical chemistry. B</title><addtitle>J. Phys. Chem. B</addtitle><description>The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be an active catalyst for the dehydrochlorination reaction, so the rate of 1-chlorobutane conversion grows significantly with time. Changes in the MgO texture during the topochemical reaction are discussed and their effect on the catalytic activity is estimated.</description><issn>1520-6106</issn><issn>1520-5207</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNo9kMtOwzAURCMEEqWw4A-8YRnwI3GSZRXRh1RaBEEsrVvHaVxSp7JdaL6A3yaliMXojjRHo6sJgluC7wmm5GGzw5hlGc_OggGJKQ57Jed_nhPML4Mr5zYY05imfBB85zWYtXJIG1Sog99bhcCUKAcPTee1RCPp9af2HWortADTStu5Pmu0UehpvUTl3mqzRjPvUGHBuKq1W_C6Nci3PZA39Njta4VeFMjf4Ev7GpEwr5vWtqu9B6Oug4sKGqdu_u4weBs_Fvk0nC8ns3w0D4FS4sO0qmimopjHcSUVh4hTGaVYslgxLjkGhVlUZTSJIEtVuSpTxaI0IUpWEWZlxoZBeOrVzquD2Fm9BdsJsB-CJyyJRfH8Kibzcfa-wLmY9vzdiQfpxKbdW9N_JwgWx7XF_9rsBwa3cok</recordid><startdate>20010510</startdate><enddate>20010510</enddate><creator>Fenelonov, Vladimir B</creator><creator>Mel'gunov, Maxim S</creator><creator>Mishakov, Ilya V</creator><creator>Richards, Ryan M</creator><creator>Chesnokov, Vladimir V</creator><creator>Volodin, Alexander M</creator><creator>Klabunde, Kenneth J</creator><general>American Chemical Society</general><scope>BSCLL</scope></search><sort><creationdate>20010510</creationdate><title>Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane</title><author>Fenelonov, Vladimir B ; Mel'gunov, Maxim S ; Mishakov, Ilya V ; Richards, Ryan M ; Chesnokov, Vladimir V ; Volodin, Alexander M ; Klabunde, Kenneth J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a221t-8ff29e45655fce6a462c480c35e36c60ae034f9274a98edbd8e34871ecf403d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fenelonov, Vladimir B</creatorcontrib><creatorcontrib>Mel'gunov, Maxim S</creatorcontrib><creatorcontrib>Mishakov, Ilya V</creatorcontrib><creatorcontrib>Richards, Ryan M</creatorcontrib><creatorcontrib>Chesnokov, Vladimir V</creatorcontrib><creatorcontrib>Volodin, Alexander M</creatorcontrib><creatorcontrib>Klabunde, Kenneth J</creatorcontrib><collection>Istex</collection><jtitle>The journal of physical chemistry. B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fenelonov, Vladimir B</au><au>Mel'gunov, Maxim S</au><au>Mishakov, Ilya V</au><au>Richards, Ryan M</au><au>Chesnokov, Vladimir V</au><au>Volodin, Alexander M</au><au>Klabunde, Kenneth J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane</atitle><jtitle>The journal of physical chemistry. B</jtitle><addtitle>J. Phys. Chem. B</addtitle><date>2001-05-10</date><risdate>2001</risdate><volume>105</volume><issue>18</issue><spage>3937</spage><epage>3941</epage><pages>3937-3941</pages><issn>1520-6106</issn><eissn>1520-5207</eissn><abstract>The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be an active catalyst for the dehydrochlorination reaction, so the rate of 1-chlorobutane conversion grows significantly with time. Changes in the MgO texture during the topochemical reaction are discussed and their effect on the catalytic activity is estimated.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp0039969</doi><tpages>5</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1520-6106
ispartof	The journal of physical chemistry. B, 2001-05, Vol.105 (18), p.3937-3941
issn	1520-6106 1520-5207
language	eng
recordid	cdi_istex_primary_ark_67375_TPS_GLF9WN0C_H
source	ACS Publications
title	Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T01%3A04%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_istex&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Changes%20in%20Texture%20and%20Catalytic%20Activity%20of%20Nanocrystalline%20MgO%20during%20Its%20Transformation%20to%20MgCl2%20in%20the%20Reaction%20with%201-Chlorobutane&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20B&rft.au=Fenelonov,%20Vladimir%20B&rft.date=2001-05-10&rft.volume=105&rft.issue=18&rft.spage=3937&rft.epage=3941&rft.pages=3937-3941&rft.issn=1520-6106&rft.eissn=1520-5207&rft_id=info:doi/10.1021/jp0039969&rft_dat=%3Cacs_istex%3Ea236613683%3C/acs_istex%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true