Photofragment Imaging of CH3Br+ from (CH3Br)2 + at 355 nm

Photofragment Imaging of CH3Br+ from (CH3Br)2 + at 355 nm

Photodissociation of (CH3Br)2 + was studied at 355 nm with photofragment imaging spectroscopy for the product CH3Br+. The center-of-mass translational energy distribution is represented by a Gaussian distribution that peaks at 25 kcal mol-1. The angular distribution is characterized by the anisotrop...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1997-02, Vol.101 (7), p.1227-1230
Hauptverfasser: Suto, Kunihiro, Sato, Yoshihiro, Matsumi, Yutaka, Kawasaki, Masahiro
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container_issue 7
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container_title The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
container_volume 101
creator Suto, Kunihiro
Sato, Yoshihiro
Matsumi, Yutaka
Kawasaki, Masahiro
description Photodissociation of (CH3Br)2 + was studied at 355 nm with photofragment imaging spectroscopy for the product CH3Br+. The center-of-mass translational energy distribution is represented by a Gaussian distribution that peaks at 25 kcal mol-1. The angular distribution is characterized by the anisotropy parameter β = 1.8 ± 0.2. Photodissociation dynamics of the ion dimer at 355 nm is discussed.
doi_str_mv 10.1021/jp9629304
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title Photofragment Imaging of CH3Br+ from (CH3Br)2 + at 355 nm
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