Terminal Coordination of a Gallium(I) Species to a Transition Metal. Syntheses and Crystal Structures of Ru{GaCl(THF)2}{GaCl2(THF)}2(CO)3·0.5THF and Ru2{GaCl2(THF)}2(CO)8

The reaction of Ru3(CO)12 with Ga2Cl4 in the presence of gallium metal in refluxing toluene, followed by crystallization from tetrahydrofuran, produces Ru{GaCl(THF)2}{GaCl2(THF)}2(CO)3·0.5 THF (1) and Ru2{GaCl2(THF)}2(CO)8 (2) (THF = tetrahydrofuran). The ruthenium atom in 1 has an approximately oct...

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Veröffentlicht in:	Inorganic chemistry 1997-06, Vol.36 (13), p.2704-2707
Hauptverfasser:	Harakas, George N, Whittlesey, Bruce R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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