Kinetics and Mechanism of Nucleophilic Substitutions on Coordinated Polyenes and Polyenyls. 3. Activation of η5-Cyclopentadienyl Ligands toward Nucleophilic Attack through η5 → η3 Ring Slippage and a Comparison with Reaction at C5H4O in [Ru(η5-C5H5)(η4-C5H4O)(L)]+ (L = CH3CN, Pyridine, Thiourea)

Complexes of the types [Ru(η5-C5H5)(η4-C5H4O)]2(CF3SO3)2 (1) and [Ru(η5-C5H5)(η4-C5H4O)(L)]CF3SO3 (L = CH3CN (2), pyridine (3), thiourea (4)) react with tertiary phosphines to give (i) 1,1‘- (12) or (ii) 1,2-disubstituted ruthenocenes (13) depending primarily on the basicity of the entering phosphin...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 1998-12, Vol.17 (26), p.5674-5688
Hauptverfasser:	Simanko, Walter, Tesch, Walter, Sapunov, Valentin N, Mereiter, Kurt, Schmid, Roland, Kirchner, Karl, Coddington, John, Wherland, Scot
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!