Partially Bound Systems as Sensitive Probes of Microsolvation:  A Microwave and ab Initio Study of HCN···HCN−BF3

The complex HCN···HCN−BF3 has been investigated by rotational spectroscopy and ab initio methods. The experimental B−N bond distance is 2.299(28) Å, which represents a contraction of 0.174(57) Å relative to that previously determined in HCN−BF3. The observed N···H distance, on the other hand, is 2.1...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2003-04, Vol.107 (16), p.2808-2814
Hauptverfasser:	Fiacco, D. L, Leopold, K. R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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