Preparation, Structural Characterization, and Reactions of Tantalum-Alkyne Complexes TaCl3(R1C⋮CR2)L2 (L2 = DME, Bipy, and TMEDA; L = Py)

Tantalum-alkyne complexes with the general formula TaCl3(R1C⋮CR2)(dme) (1a, R1 = R2 = Et; 1b, R1 = R2 = n-C5H11; 1c, R1 = Ph, R2 = Me; 1d, R1 = R2 = Ph; DME = 1,2-dimethoxyethane) were synthesized by treatment of the corresponding alkynes with a low-valent tantalum derived by reduction of tantalum p...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2003-02, Vol.22 (3), p.464-472
Hauptverfasser: Oshiki, Toshiyuki, Tanaka, Kouji, Yamada, Jun, Ishiyama, Takaya, Kataoka, Yasutaka, Mashima, Kazushi, Tani, Kazuhide, Takai, Kazuhiko
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!