Palladium-Assisted Formation of Carbon−Carbon Bonds. 8. Synthesis and Reactivity toward Internal Alkynes, Carbon Monoxide, and Isocyanides of Orthopalladated Dibenzylamine Complexes

By refluxing of dibenzylamine and [Pd(OAc)2]3 (3.2:1) in acetone, the orthometalated complex [Pd{C6H4(CH2NHCH2Ph)-2}(μ-OAc)]2 (1) is obtained. Metathetical reaction of 1 with NaBr affords the corresponding bromo-bridging dimer [Pd{C6H4(CH2NHCH2Ph)-2}(μ-Br)]2 (2). Neutral ligands split the bromo brid...

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Veröffentlicht in:	Organometallics 1999-07, Vol.18 (14), p.2683-2693
Hauptverfasser:	Vicente, José, Saura-Llamas, Isabel, Turpín, Juana, Ramírez de Arellano, M. Carmen, Jones, Peter G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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