Deuterium Kinetic Isotope Effects in the Gas-Phase SN2 Reactions of Solvated Fluoride Ions with Methyl Halides

Rate constants and deuterium kinetic isotope effects (KIEs) are measured for gas-phase nucleophilic substitution (SN2) reactions of solvated fluoride ions of F-(methanol) + CH3X (X = Br, I), F-(isopropyl alcohol) + CH3I, and F-(hydrogen fluoride) + CH3I at 300 K. The isotope effects are determined a...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-11, Vol.108 (45), p.9887-9891
Hauptverfasser:	Kato, Shuji, Hacaloglu, Jale, Davico, Gustavo E, DePuy, Charles H, Bierbaum, Veronica M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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