Associating Borate and Silicate Chemistry by Extreme Conditions:  High-Pressure Synthesis, Crystal Structure, and Properties of the New Borates RE3B5O12 (RE = Er−Lu)

The rare-earth borates RE3B5O12 (RE = Er−Lu) were prepared by use of high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 10 GPa and 1100 °C. All compounds crystallize in a novel structure type and possess a new composition, unknown in borate chemistry until now. In...

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Veröffentlicht in:Chemistry of materials 2005-05, Vol.17 (10), p.2707-2715
Hauptverfasser: Emme, Holger, Valldor, Martin, Pöttgen, Rainer, Huppertz, Hubert
Format: Artikel
Sprache:eng
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