Na2Te3Mo3O16:  A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

Na2Te3Mo3O16:  A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

The synthesis, structure, and characterization of a new noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16, are reported. Na2Te3Mo3O16 crystallizes in the noncentrosymmetric monoclinic space group I2 (No. 5, cell choice 3) with a = 7.3373(10) Å, b = 11.2668(16) Å, c = 8.2369(18) Å, and β = 97.387...

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Veröffentlicht in:Chemistry of materials 2006-04, Vol.18 (8), p.2070-2074
Hauptverfasser: Chi, Eun Ok, Ok, Kang Min, Porter, Yetta, Halasyamani, P. Shiv
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creator Chi, Eun Ok
Ok, Kang Min
Porter, Yetta
Halasyamani, P. Shiv
description The synthesis, structure, and characterization of a new noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16, are reported. Na2Te3Mo3O16 crystallizes in the noncentrosymmetric monoclinic space group I2 (No. 5, cell choice 3) with a = 7.3373(10) Å, b = 11.2668(16) Å, c = 8.2369(18) Å, and β = 97.387(3)°. The material exhibits a quasi-one-dimensional crystal structure, with each chain consisting of edge-shared MoO6 octahedra that are connected by TeO3 and TeO4 polyhedra. The SHG efficiency of Na2Te3Mo3O16, using 1064 nm radiation, is approximately 500 × α-SiO2 and is phase-matchable (type 1). The strong SHG efficiency is maintained up to the melting temperature. The maximum polarization is 0.189 μC/cm2 at 25 kV/cm, and the pyroelectric coefficient (total effect), p, is −2.6 μC/m2 K.
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Shiv</creator><creatorcontrib>Chi, Eun Ok ; Ok, Kang Min ; Porter, Yetta ; Halasyamani, P. Shiv</creatorcontrib><description>The synthesis, structure, and characterization of a new noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16, are reported. Na2Te3Mo3O16 crystallizes in the noncentrosymmetric monoclinic space group I2 (No. 5, cell choice 3) with a = 7.3373(10) Å, b = 11.2668(16) Å, c = 8.2369(18) Å, and β = 97.387(3)°. The material exhibits a quasi-one-dimensional crystal structure, with each chain consisting of edge-shared MoO6 octahedra that are connected by TeO3 and TeO4 polyhedra. The SHG efficiency of Na2Te3Mo3O16, using 1064 nm radiation, is approximately 500 × α-SiO2 and is phase-matchable (type 1). The strong SHG efficiency is maintained up to the melting temperature. 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Shiv</creatorcontrib><collection>Istex</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chi, Eun Ok</au><au>Ok, Kang Min</au><au>Porter, Yetta</au><au>Halasyamani, P. Shiv</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Na2Te3Mo3O16:  A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2006-04-18</date><risdate>2006</risdate><volume>18</volume><issue>8</issue><spage>2070</spage><epage>2074</epage><pages>2070-2074</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>The synthesis, structure, and characterization of a new noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O16, are reported. Na2Te3Mo3O16 crystallizes in the noncentrosymmetric monoclinic space group I2 (No. 5, cell choice 3) with a = 7.3373(10) Å, b = 11.2668(16) Å, c = 8.2369(18) Å, and β = 97.387(3)°. The material exhibits a quasi-one-dimensional crystal structure, with each chain consisting of edge-shared MoO6 octahedra that are connected by TeO3 and TeO4 polyhedra. The SHG efficiency of Na2Te3Mo3O16, using 1064 nm radiation, is approximately 500 × α-SiO2 and is phase-matchable (type 1). The strong SHG efficiency is maintained up to the melting temperature. The maximum polarization is 0.189 μC/cm2 at 25 kV/cm, and the pyroelectric coefficient (total effect), p, is −2.6 μC/m2 K.</abstract><pub>American Chemical Society</pub><doi>10.1021/cm052614e</doi><tpages>5</tpages></addata></record>
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title Na2Te3Mo3O16:  A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties
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