Concise Syntheses of (−)- and (+)-Syringolide 1 and (−)-Δ7-Syringolide 1

(−)- and (+)-Syringolide 1 have been synthesized from 2,3-O-isopropylidene-β-threo-pentulofuranose (1), which was readily prepared from d- or l-xylose, respectively. Condensation of 1 with 3-oxooctanoic acid and treatment of the ester with TFA:H2O (9:1) produced syringolide 1 in 6.3% yield for the t...

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Veröffentlicht in:	Journal of organic chemistry 1997-07, Vol.62 (14), p.4780-4784
Hauptverfasser:	Zeng, Chun-min, Midland, Sharon L, Keen, Noel T, Sims, James J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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