s-trans-Diene Complexes of a First-Row Transition Metal. Half-Sandwich s-trans-η4-1,3-Diene Nitrosyl Complexes of Chromium

The first s-trans-1,3-diene complexes of a first-row transition metal have been prepared and characterized both in solution and in the solid state. The unexpected s-trans configuration was obtained from photolytic decarbonylation of Cp‘Cr(NO)(CO)2 (Cp‘ = η5-C5H5 and η5-C5Me5) in the presence of conj...

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Veröffentlicht in:Organometallics 2006-05, Vol.25 (11), p.2705-2708
Hauptverfasser: Norman, David W, Ferguson, Michael J, McDonald, Robert, Stryker, Jeffrey M
Format: Artikel
Sprache:eng
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