Molybdenum η3-Allyl Dicarbonyl Complexes as a New Class of Precursors for Highly Reactive Epoxidation Catalysts with tert-Butyl Hydroperoxide

New Mo(II) diimine derivatives of [Mo(η3-allyl)X(CO)2(CH3CN)2] (allyl = C3H5 and C5H5O; X = Cl, Br) were prepared, and [Mo(η3-C3H5)Cl(CO)2(BIAN)] (BIAN = 1,4-(4-chloro)phenyl-2,3-naphthalenediazabutadiene) (7) was structurally characterized by single-crystal X-ray diffraction. This complex adopted a...

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Veröffentlicht in:	Organometallics 2007-11, Vol.26 (23), p.5548-5556
Hauptverfasser:	Alonso, João C, Neves, Patrícia, Pires da Silva, Maria João, Quintal, Susana, Vaz, Pedro D, Silva, Carlos, Valente, Anabela A, Ferreira, Paula, Calhorda, Maria José, Félix, Vitor, Drew, Michael G. B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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