Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study
In recent years, metallic tin and tin compounds have proven to be interesting electrode materials for lithium batteries. However, detailed information about the mechanism of reaction in phosphate compounds is needed to improve the performance of some previously examined and future electrode material...
Gespeichert in:
| Veröffentlicht in: | Journal of physical chemistry. C 2008-11, Vol.112 (44), p.17436-17442 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 17442 |
|---|---|
| container_issue | 44 |
| container_start_page | 17436 |
| container_title | Journal of physical chemistry. C |
| container_volume | 112 |
| creator | Corredor, J. I León, B Pérez Vicente, C Tirado, J. L |
| description | In recent years, metallic tin and tin compounds have proven to be interesting electrode materials for lithium batteries. However, detailed information about the mechanism of reaction in phosphate compounds is needed to improve the performance of some previously examined and future electrode materials containing these species. In the present work, powerful techniques for the study of the local environments of the atoms, such as 119Sn Mössbauer spectrometry and 7Li and 31P MAS NMR, are used to obtain basic information on the processes involved during the discharge/reduction of the electrode material. The results allow extracting valuable information about the possible interactions between the participating atoms and the surrounding framework. |
| doi_str_mv | 10.1021/jp800722x |
| format | Article |
| fullrecord | <record><control><sourceid>istex_acs_j</sourceid><recordid>TN_cdi_istex_primary_ark_67375_TPS_3NGXD716_3</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_3NGXD716_3</sourcerecordid><originalsourceid>FETCH-LOGICAL-a683-6bd4e0cd89412b19239a37dc07fddf8e63606fea14f6b9be34ec17cc687baa713</originalsourceid><addsrcrecordid>eNo9UEtOwzAUtBBIlMKCG3jDjoAdJ3bCriqlRUo_arpgZzn-qClJHMWJaA_CfUlb1NXMaEbvjQaAR4xeMPLx666OEGK-v78CAxwT32NBGF5feMBuwZ1zO4RCgjAZgN_ESlHAiTFatg5aA9uthpOiV42VW13mR3uthWxzWx39JG-3eVfCnx5hWvnjYrUMoKhUL2Y9fYMjOLZllldaQYJXz5AlOZyPUriYr085jOO0gnPrXCY63cC0Pn1z0tYHmLadOtyDGyMKpx_-cQg2H5PNeOYly-nneJR4gkbEo5kKNJIqigPsZzj2SSwIUxIxo5SJNCUUUaMFDgzN4kyTQEvMpKQRy4RgmAyBdz6bu1bved3kpWgOXDTfnDLCQr5ZpZwspl_vDFNO-vzTOS-k4zvbNVVfjmPEj9Pzy_TkD2AqdCM</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study</title><source>ACS Publications</source><creator>Corredor, J. I ; León, B ; Pérez Vicente, C ; Tirado, J. L</creator><creatorcontrib>Corredor, J. I ; León, B ; Pérez Vicente, C ; Tirado, J. L</creatorcontrib><description>In recent years, metallic tin and tin compounds have proven to be interesting electrode materials for lithium batteries. However, detailed information about the mechanism of reaction in phosphate compounds is needed to improve the performance of some previously examined and future electrode materials containing these species. In the present work, powerful techniques for the study of the local environments of the atoms, such as 119Sn Mössbauer spectrometry and 7Li and 31P MAS NMR, are used to obtain basic information on the processes involved during the discharge/reduction of the electrode material. The results allow extracting valuable information about the possible interactions between the participating atoms and the surrounding framework.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp800722x</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Energy Conversion and Storage</subject><ispartof>Journal of physical chemistry. C, 2008-11, Vol.112 (44), p.17436-17442</ispartof><rights>Copyright © 2008 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp800722x$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp800722x$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,27067,27915,27916,56729,56779</link.rule.ids></links><search><creatorcontrib>Corredor, J. I</creatorcontrib><creatorcontrib>León, B</creatorcontrib><creatorcontrib>Pérez Vicente, C</creatorcontrib><creatorcontrib>Tirado, J. L</creatorcontrib><title>Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>In recent years, metallic tin and tin compounds have proven to be interesting electrode materials for lithium batteries. However, detailed information about the mechanism of reaction in phosphate compounds is needed to improve the performance of some previously examined and future electrode materials containing these species. In the present work, powerful techniques for the study of the local environments of the atoms, such as 119Sn Mössbauer spectrometry and 7Li and 31P MAS NMR, are used to obtain basic information on the processes involved during the discharge/reduction of the electrode material. The results allow extracting valuable information about the possible interactions between the participating atoms and the surrounding framework.</description><subject>C: Energy Conversion and Storage</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNo9UEtOwzAUtBBIlMKCG3jDjoAdJ3bCriqlRUo_arpgZzn-qClJHMWJaA_CfUlb1NXMaEbvjQaAR4xeMPLx666OEGK-v78CAxwT32NBGF5feMBuwZ1zO4RCgjAZgN_ESlHAiTFatg5aA9uthpOiV42VW13mR3uthWxzWx39JG-3eVfCnx5hWvnjYrUMoKhUL2Y9fYMjOLZllldaQYJXz5AlOZyPUriYr085jOO0gnPrXCY63cC0Pn1z0tYHmLadOtyDGyMKpx_-cQg2H5PNeOYly-nneJR4gkbEo5kKNJIqigPsZzj2SSwIUxIxo5SJNCUUUaMFDgzN4kyTQEvMpKQRy4RgmAyBdz6bu1bved3kpWgOXDTfnDLCQr5ZpZwspl_vDFNO-vzTOS-k4zvbNVVfjmPEj9Pzy_TkD2AqdCM</recordid><startdate>20081106</startdate><enddate>20081106</enddate><creator>Corredor, J. I</creator><creator>León, B</creator><creator>Pérez Vicente, C</creator><creator>Tirado, J. L</creator><general>American Chemical Society</general><scope>BSCLL</scope></search><sort><creationdate>20081106</creationdate><title>Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study</title><author>Corredor, J. I ; León, B ; Pérez Vicente, C ; Tirado, J. L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a683-6bd4e0cd89412b19239a37dc07fddf8e63606fea14f6b9be34ec17cc687baa713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>C: Energy Conversion and Storage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Corredor, J. I</creatorcontrib><creatorcontrib>León, B</creatorcontrib><creatorcontrib>Pérez Vicente, C</creatorcontrib><creatorcontrib>Tirado, J. L</creatorcontrib><collection>Istex</collection><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Corredor, J. I</au><au>León, B</au><au>Pérez Vicente, C</au><au>Tirado, J. L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2008-11-06</date><risdate>2008</risdate><volume>112</volume><issue>44</issue><spage>17436</spage><epage>17442</epage><pages>17436-17442</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>In recent years, metallic tin and tin compounds have proven to be interesting electrode materials for lithium batteries. However, detailed information about the mechanism of reaction in phosphate compounds is needed to improve the performance of some previously examined and future electrode materials containing these species. In the present work, powerful techniques for the study of the local environments of the atoms, such as 119Sn Mössbauer spectrometry and 7Li and 31P MAS NMR, are used to obtain basic information on the processes involved during the discharge/reduction of the electrode material. The results allow extracting valuable information about the possible interactions between the participating atoms and the surrounding framework.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp800722x</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1932-7447 |
| ispartof | Journal of physical chemistry. C, 2008-11, Vol.112 (44), p.17436-17442 |
| issn | 1932-7447 1932-7455 |
| language | eng |
| recordid | cdi_istex_primary_ark_67375_TPS_3NGXD716_3 |
| source | ACS Publications |
| subjects | C: Energy Conversion and Storage |
| title | Local Effects of the Electrochemical Reaction of Lithium with Sn2ClPO4 and SnHPO4: A Combined 31P, 7Li MAS NMR and 119Sn Mossbauer Spectroscopy Study |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T06%3A11%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_acs_j&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Local%20Effects%20of%20the%20Electrochemical%20Reaction%20of%20Lithium%20with%20Sn2ClPO4%20and%20SnHPO4:%20A%20Combined%2031P,%207Li%20MAS%20NMR%20and%20119Sn%20Mossbauer%20Spectroscopy%20Study&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Corredor,%20J.%20I&rft.date=2008-11-06&rft.volume=112&rft.issue=44&rft.spage=17436&rft.epage=17442&rft.pages=17436-17442&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/jp800722x&rft_dat=%3Cistex_acs_j%3Eark_67375_TPS_3NGXD716_3%3C/istex_acs_j%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |