Crystal Structure of [PPN+][Cr(CO)4NO-]:  Calculations and Comparisons of Cr(CO)4NO- with Mn(CO)5

The crystal structure of the deep red crystalline salt PPN+Cr(CO)4NO- has been determined and can be described as a distorted trigonal bipyramid. As expected, the NO group is equatorial, and the major distortion in Cr(CO)4NO- involves the axial CO groups, with an angle Cax−Cr−Cax of 159.08(17)°. The...

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Veröffentlicht in:	Organometallics 2001-08, Vol.20 (16), p.3613-3616
Hauptverfasser:	Sorensen, Ted S, Sun, Fang, McDonald, Robert
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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