Solvation Induced Vibrational Peak Shift of a Re Bipyridyl Complex in Solution and at the Nanoporous ZrO2/Liquid Interface
In this paper, we compare the solvation induced vibrational peak shift of Re(CO)3(Cl)(2,2‘-bipyridine-4,4‘-carboxylate) in solution and at nanocrystal/liquid interfaces. Upon optical excitation to its MLCT excited state, an instantaneous blue shift in CO stretching frequency is observed, which is fo...
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| Veröffentlicht in: | The journal of physical chemistry. B 2004-10, Vol.108 (41), p.16194-16200 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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