Coupling H2 to Electron Transfer with a 17-Electron Heterobimetallic Hydride:  A “Redox Switch” Model for the H2-Activating Center of Hydrogenase

A meta-stable heterobimetallic mixed-valence ion, [Fe(II),Ru(III)], is formed by the one-electron oxidation of Cp*(dppf)RuH {1, dppf = 1,1‘-bis(diphenylphosphino)ferrocene, Cp* = pentamethylcyclopentadienide}. A remarkable stability toward one-electron oxidation is revealed by the cyclic voltammetry...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-01, Vol.118 (4), p.798-803
Hauptverfasser:	Hembre, Robert T, McQueen, J. Scott, Day, Victor W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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