Effect of Conformational Constraints on Gated Electron-Transfer Kinetics. 3. Copper(II/I) Complexes with cis- and trans-Cyclopentanediyl-1,4,8,11-tetrathiacyclotetradecane1

Previous kinetic and electrochemical studies of copper complexes with macrocyclic tetrathiaetherssuch as 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4)have indicated that electron transfer and the accompanying conformational change occur sequentially to give rise to a dual-pathway mechanism. Under...

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Veröffentlicht in:	Inorganic chemistry 2000-06, Vol.39 (13), p.2897-2905
Hauptverfasser:	Wijetunge, Prabodha, Kulatilleke, Chandrika P, Dressel, Luke T, Heeg, Mary Jane, Ochrymowycz, L. A, Rorabacher, D. B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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