Kinetics and Mechanism of Reversible Oxidative Addition of Hydrogen across the Metal−Metal Bond of (μ-H)2Ru3(CO)8(μ-P(t-Bu)2)2. Steric Promotion of Metal−Metal Bond Cleavage But a CO Dissociative Mechanism

The kinetics of the reaction (μ-H)2Ru3(CO)8(μ-P(t-Bu)2)2 + H2 ⇄ (μ-H)2Ru3(CO)8(H)2(μ-P(t-Bu)2)2 have been studied. The reaction of (μ-H)2Ru3(CO)8(μ-P(t-Bu)2)2 with H2 has a rate law which is first-order in cluster concentration and in hydrogen pressure and inverse order in CO pressure; on the basis...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-11, Vol.118 (47), p.11805-11812
Hauptverfasser:	Safarowic, Fred J, Bierdeman, David J, Keister, Jerome B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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