C−C Activation in Biphenylene. Synthesis, Structure, and Reactivity of (C5Me5)2M2(2,2‘-biphenyl) (M = Rh, Co)

Carbon−carbon bond cleavage of biphenylene was achieved with (C5Me5)M(C2H4)2 (M = Rh, Co) to give the bimetallic species (C5Me5)2M2(2,2‘-biphenyl). The isomorphous solid state X-ray structures of these complexes showed the biphenyl substrate to be σ-coordinated to one metal and η4-bound to the other...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organometallics 1997-05, Vol.16 (10), p.2016-2023
Hauptverfasser:	Perthuisot, Christophe, Edelbach, Brian L, Zubris, Deanna L, Jones, William D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!