Flux Growth of Vanadyl Pyrophosphate, (VO)2P2O7, and Spin Dimer Analysis of the Spin Exchange Interactions of (VO)2P2O7 and Vanadyl Hydrogen Phosphate, VO(HPO4)·0.5H2O

Large transparent blue crystals of vanadyl pyrophosphate, (VO)2P2O7, were grown from a phosphorus pentoxide flux, and the single-crystal X-ray structure of (VO)2P2O7 was determined with high precision. On the basis of spin dimer analysis, we examined the spin exchange interactions of (VO)2P2O7 and i...

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Veröffentlicht in:	Inorganic chemistry 2002-09, Vol.41 (18), p.4664-4672
Hauptverfasser:	Koo, Hyun-Joo, Whangbo, Myung-Hwan, VerNooy, Paul D, Torardi, Charlie C, Marshall, William J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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