Synthesis, Structural, and Theoretical Analysis of Ru4(CO)12(μ-PF2)(μ4-P):  Is the μ4-P Atom a Three-Electron or a Five-Electron Donor?

The X-ray molecular structure of Ru4(CO)12(μ-PF2)(μ4-P) exhibits a rather open Ru4 butterfly with no Ru−Ru bond along the butterfly hinge, which is bridged by a μ-PF2 ligand. The μ4-P atom unsymmetrically bridges the Ru4 butterfly with two very different Ru−P−Ru angles:  148.71(15) and 95.43(10)°. T...

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Veröffentlicht in:	Organometallics 2001-10, Vol.20 (22), p.4469-4475
Hauptverfasser:	Kahlal, Samia, Wang, Weibin, Scoles, Ludmila, Udachin, Konstantin A, Saillard, Jean-Yves, Carty, Arthur J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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