Structure and Thermodynamics of NaF−AlF3 Melts with Addition of CaF2 and MgF2

The NaF−AlF3 system with additions of CaF2 and MgF2 has been studied with Raman and vapor pressure measurements for 3 ≥ CR (NaF/AlF3 molar ratio) ≥ 1 and up to 50 mol % additive. The results show that the binary melt can be described using the two equilibria AlF6 3- = AlF6 2- + F- and AlF5 2- = AlF4...

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Veröffentlicht in:	Inorganic chemistry 1996-07, Vol.35 (14), p.4198-4210
Hauptverfasser:	Gilbert, Bernard, Robert, Eric, Tixhon, Eric, Olsen, Jørn E, Østvold, Terje
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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