$Molecular Structure of the Aluminum Halides, Al2Cl6, AlCl3, Al2Br6, AlBr3, and AlI3, Obtained by Gas-Phase Electron-Diffraction and ab Initio Molecular Orbital Calculations$

Molecular Structure of the Aluminum Halides, Al2Cl6, AlCl3, Al2Br6, AlBr3, and AlI3, Obtained by Gas-Phase Electron-Diffraction and ab Initio Molecular Orbital Calculations

Gas-phase electron-diffraction (GED) data together with results from ab initio molecular orbital and normal coordinate calculations have been used to determine the structures of the aluminum trihalides AlX3 (X = Cl, Br, I) and the chloride and bromide dimers Al2Cl6 and Al2Br6. No monomeric species w...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1999-03, Vol.103 (11), p.1644-1652
Hauptverfasser:	Aarset, Kirsten, Shen, Quang, Thomassen, Hanne, Richardson, Alan D, Hedberg, Kenneth
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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