Tape-Cast Water-Stable NASICON-Type High Lithium Ion Conducting Solid Electrolyte Films for Aqueous Lithium-Air Batteries

Tape-Cast Water-Stable NASICON-Type High Lithium Ion Conducting Solid Electrolyte Films for Aqueous Lithium-Air Batteries

A Li1.4Al0.4Ge0.2Ti1.4 (PO4)3 (LAGTP) film was prepared by a tape-casting method using a fine LAGTP powder prepared by the sol-gel method. A LAGTP composite film formed with approximately 2 wt% epoxy resin was water-impermeable and had high mechanical strength. The highest lithium ion conductivity o...

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Veröffentlicht in:Journal of the Electrochemical Society 2015-01, Vol.162 (7), p.A1265-A1271
Hauptverfasser: Zhang, Peng, Wang, Hui, Lee, Yong-Gun, Matsui, Masaki, Takeda, Yasuo, Yamamoto, Osamu, Imanishi, Nobuyuki
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container_end_page A1271
container_issue 7
container_start_page A1265
container_title Journal of the Electrochemical Society
container_volume 162
creator Zhang, Peng
Wang, Hui
Lee, Yong-Gun
Matsui, Masaki
Takeda, Yasuo
Yamamoto, Osamu
Imanishi, Nobuyuki
description A Li1.4Al0.4Ge0.2Ti1.4 (PO4)3 (LAGTP) film was prepared by a tape-casting method using a fine LAGTP powder prepared by the sol-gel method. A LAGTP composite film formed with approximately 2 wt% epoxy resin was water-impermeable and had high mechanical strength. The highest lithium ion conductivity of 5.26 × 10−4 S cm−1 at 25°C was obtained for the LAGTP-epoxy resin composite film. The LAGTP-epoxy resin composite film was stable in an aqueous solution with a high content of lithium ions. The three-point bending strength of the 75 μm thick LAGTP-epoxy resin composite film was 125 N mm−2. The water-impermeable composite film with excellent mechanical properties is an attractive candidate for the water-stable lithium electrode in rechargeable aqueous lithium-air batteries.
doi_str_mv 10.1149/2.0711507jes
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title Tape-Cast Water-Stable NASICON-Type High Lithium Ion Conducting Solid Electrolyte Films for Aqueous Lithium-Air Batteries
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