LiNi0.4Mn1.6O4/Electrolyte and Carbon Black/Electrolyte High Voltage Interfaces: To Evidence the Chemical and Electronic Contributions of the Solvent on the Cathode-Electrolyte Interface Formation

Solvent and lithium salt decomposition products on LiNixMnyO4-type electrodes are known to be ROM, ROCO2M (M = Li, Ni, Mn), LiF, LixPFyOz, polycarbonates and polyethers. These compounds are chemically formed due to the high nucleophilic character of spinel oxide and LiPF6 decomposition. The high pot...

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Veröffentlicht in:	Journal of the Electrochemical Society 2012-01, Vol.159 (11), p.A1880-A1890
Hauptverfasser:	Demeaux, Julien, Caillon-Caravanier, Magaly, Galiano, Hervé, Lemordant, Daniel, Claude-Montigny, Bénédicte
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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