Effect of Calcination Temperature on a P-type Na0.6Mn0.65Ni0.25Co0.10O2 Cathode Material for Sodium-Ion Batteries

Unstable and deficient supplies of lithium resources have led to the development of alternative battery systems such as sodium-ion batteries. Herein, P-type Na0.6Mn0.65Ni0.25Co0.10O2 cathode materials were synthesized by a co-precipitation and solid-state reaction method. When the calcination temper...

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Veröffentlicht in:Journal of the Electrochemical Society 2017-01, Vol.164 (1), p.A6308-A6314
Hauptverfasser: Nguyen, Ngoc-Anh, Kim, Kyuman, Choi, Kwang Ho, Jeon, Hyunkyu, Lee, Kyubock, Ryou, Myung-Hyun, Lee, Yong Min
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container_issue 1
container_start_page A6308
container_title Journal of the Electrochemical Society
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creator Nguyen, Ngoc-Anh
Kim, Kyuman
Choi, Kwang Ho
Jeon, Hyunkyu
Lee, Kyubock
Ryou, Myung-Hyun
Lee, Yong Min
description Unstable and deficient supplies of lithium resources have led to the development of alternative battery systems such as sodium-ion batteries. Herein, P-type Na0.6Mn0.65Ni0.25Co0.10O2 cathode materials were synthesized by a co-precipitation and solid-state reaction method. When the calcination temperature was changed from 700 to 1000°C, Na0.6Mn0.65Ni0.25Co0.10O2 had a different morphology and crystalline structure; however, a P3-type structure was formed only at 700°C, and P2-type structured cathodes could be obtained at 800, 900, and 1000°C. Their electrochemical performances were evaluated with 2032 coin-type half cells. Among them, the P2-type cathode calcinated at 900°C, exhibited a high specific discharge capacity of 148 mAh g−1, and a stable cycling performance at a 0.2 C rate for 150 cycles.
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title Effect of Calcination Temperature on a P-type Na0.6Mn0.65Ni0.25Co0.10O2 Cathode Material for Sodium-Ion Batteries
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