Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions

Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions

Ion-solvent interactions play a crucial role in secondary battery systems: the desolvation of ions at an electrode/electrolyte interface can be the rate-determining step of a battery reaction, for instance. The present theoretical study investigates the interactions between K ions and organic electr...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the Electrochemical Society 2017-01, Vol.164 (2), p.A54-A60
Hauptverfasser: Okoshi, Masaki, Yamada, Yuki, Komaba, Shinichi, Yamada, Atsuo, Nakai, Hiromi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page A60
container_issue 2
container_start_page A54
container_title Journal of the Electrochemical Society
container_volume 164
creator Okoshi, Masaki
Yamada, Yuki
Komaba, Shinichi
Yamada, Atsuo
Nakai, Hiromi
description Ion-solvent interactions play a crucial role in secondary battery systems: the desolvation of ions at an electrode/electrolyte interface can be the rate-determining step of a battery reaction, for instance. The present theoretical study investigates the interactions between K ions and organic electrolyte solvents for application in non-aqueous K-ion batteries, which have recently drawn interest as novel rechargeable batteries. Compared to Li, Na, and Mg ions, K ions display the lowest interaction energy, reflecting the large ionic radius and weak Lewis acidity of K. The weak interaction of K ions with solvents is consistent with the high rate capability exhibited by K-ion batteries and the relatively low solubility of K-ion salts observed experimentally.
doi_str_mv 10.1149/2.0211702jes
format Article
fullrecord <record><control><sourceid>iop_cross</sourceid><recordid>TN_cdi_iop_journals_10_1149_2_0211702jes</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>0211702JES</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-c90308dcc0420160ff37c07a02e037f68463fb66e6021f9ff9372629c31b86d13</originalsourceid><addsrcrecordid>eNptkMFOAjEQQBujiYje_IAePbDYaZfurjdCUEkwmIjnTem2ULK0pC0SvsMftojRi5eZzOTlHR5Ct0D6AHl1T_uEAhSErlU4Qx2o8kFWAMA56hACLMv5AC7RVQjrdEKZFx30OV8p51U0UrR4aEV7CCZgp_HERuWFjMbZgBcq7pWy-NVFEYLZbfDk-Ba2wTO_FNZIPG6VjN61h6jwm2s_lI3hAQ_xyG22wpvgLN6buMLTNJKgl6Dmex8lL2Jp1a_3Gl1o0QZ187O76P1xPB89Z9PZ02Q0nGaS8jJmsiKMlI2UJKcEONGaFZIUglBFWKF5mXOmF5wrnqroSuuKFZTTSjJYlLwB1kW9k1d6F4JXut56sxH-UAOpj0FrWv8FTfjdCTduW6_dzqda4X_0C6r8d44</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions</title><source>Institute of Physics Journals</source><creator>Okoshi, Masaki ; Yamada, Yuki ; Komaba, Shinichi ; Yamada, Atsuo ; Nakai, Hiromi</creator><creatorcontrib>Okoshi, Masaki ; Yamada, Yuki ; Komaba, Shinichi ; Yamada, Atsuo ; Nakai, Hiromi</creatorcontrib><description>Ion-solvent interactions play a crucial role in secondary battery systems: the desolvation of ions at an electrode/electrolyte interface can be the rate-determining step of a battery reaction, for instance. The present theoretical study investigates the interactions between K ions and organic electrolyte solvents for application in non-aqueous K-ion batteries, which have recently drawn interest as novel rechargeable batteries. Compared to Li, Na, and Mg ions, K ions display the lowest interaction energy, reflecting the large ionic radius and weak Lewis acidity of K. The weak interaction of K ions with solvents is consistent with the high rate capability exhibited by K-ion batteries and the relatively low solubility of K-ion salts observed experimentally.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/2.0211702jes</identifier><language>eng</language><publisher>The Electrochemical Society</publisher><ispartof>Journal of the Electrochemical Society, 2017-01, Vol.164 (2), p.A54-A60</ispartof><rights>2016 The Electrochemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c268t-c90308dcc0420160ff37c07a02e037f68463fb66e6021f9ff9372629c31b86d13</citedby><cites>FETCH-LOGICAL-c268t-c90308dcc0420160ff37c07a02e037f68463fb66e6021f9ff9372629c31b86d13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1149/2.0211702jes/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,776,780,27903,27904,53825</link.rule.ids></links><search><creatorcontrib>Okoshi, Masaki</creatorcontrib><creatorcontrib>Yamada, Yuki</creatorcontrib><creatorcontrib>Komaba, Shinichi</creatorcontrib><creatorcontrib>Yamada, Atsuo</creatorcontrib><creatorcontrib>Nakai, Hiromi</creatorcontrib><title>Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions</title><title>Journal of the Electrochemical Society</title><addtitle>J. Electrochem. Soc</addtitle><description>Ion-solvent interactions play a crucial role in secondary battery systems: the desolvation of ions at an electrode/electrolyte interface can be the rate-determining step of a battery reaction, for instance. The present theoretical study investigates the interactions between K ions and organic electrolyte solvents for application in non-aqueous K-ion batteries, which have recently drawn interest as novel rechargeable batteries. Compared to Li, Na, and Mg ions, K ions display the lowest interaction energy, reflecting the large ionic radius and weak Lewis acidity of K. The weak interaction of K ions with solvents is consistent with the high rate capability exhibited by K-ion batteries and the relatively low solubility of K-ion salts observed experimentally.</description><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNptkMFOAjEQQBujiYje_IAePbDYaZfurjdCUEkwmIjnTem2ULK0pC0SvsMftojRi5eZzOTlHR5Ct0D6AHl1T_uEAhSErlU4Qx2o8kFWAMA56hACLMv5AC7RVQjrdEKZFx30OV8p51U0UrR4aEV7CCZgp_HERuWFjMbZgBcq7pWy-NVFEYLZbfDk-Ba2wTO_FNZIPG6VjN61h6jwm2s_lI3hAQ_xyG22wpvgLN6buMLTNJKgl6Dmex8lL2Jp1a_3Gl1o0QZ187O76P1xPB89Z9PZ02Q0nGaS8jJmsiKMlI2UJKcEONGaFZIUglBFWKF5mXOmF5wrnqroSuuKFZTTSjJYlLwB1kW9k1d6F4JXut56sxH-UAOpj0FrWv8FTfjdCTduW6_dzqda4X_0C6r8d44</recordid><startdate>20170101</startdate><enddate>20170101</enddate><creator>Okoshi, Masaki</creator><creator>Yamada, Yuki</creator><creator>Komaba, Shinichi</creator><creator>Yamada, Atsuo</creator><creator>Nakai, Hiromi</creator><general>The Electrochemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170101</creationdate><title>Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions</title><author>Okoshi, Masaki ; Yamada, Yuki ; Komaba, Shinichi ; Yamada, Atsuo ; Nakai, Hiromi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-c90308dcc0420160ff37c07a02e037f68463fb66e6021f9ff9372629c31b86d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Okoshi, Masaki</creatorcontrib><creatorcontrib>Yamada, Yuki</creatorcontrib><creatorcontrib>Komaba, Shinichi</creatorcontrib><creatorcontrib>Yamada, Atsuo</creatorcontrib><creatorcontrib>Nakai, Hiromi</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Okoshi, Masaki</au><au>Yamada, Yuki</au><au>Komaba, Shinichi</au><au>Yamada, Atsuo</au><au>Nakai, Hiromi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions</atitle><jtitle>Journal of the Electrochemical Society</jtitle><addtitle>J. Electrochem. Soc</addtitle><date>2017-01-01</date><risdate>2017</risdate><volume>164</volume><issue>2</issue><spage>A54</spage><epage>A60</epage><pages>A54-A60</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Ion-solvent interactions play a crucial role in secondary battery systems: the desolvation of ions at an electrode/electrolyte interface can be the rate-determining step of a battery reaction, for instance. The present theoretical study investigates the interactions between K ions and organic electrolyte solvents for application in non-aqueous K-ion batteries, which have recently drawn interest as novel rechargeable batteries. Compared to Li, Na, and Mg ions, K ions display the lowest interaction energy, reflecting the large ionic radius and weak Lewis acidity of K. The weak interaction of K ions with solvents is consistent with the high rate capability exhibited by K-ion batteries and the relatively low solubility of K-ion salts observed experimentally.</abstract><pub>The Electrochemical Society</pub><doi>10.1149/2.0211702jes</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0013-4651
ispartof Journal of the Electrochemical Society, 2017-01, Vol.164 (2), p.A54-A60
issn 0013-4651
1945-7111
language eng
recordid cdi_iop_journals_10_1149_2_0211702jes
source Institute of Physics Journals
title Theoretical Analysis of Interactions between Potassium Ions and Organic Electrolyte Solvents: A Comparison with Lithium, Sodium, and Magnesium Ions
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T18%3A22%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-iop_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Theoretical%20Analysis%20of%20Interactions%20between%20Potassium%20Ions%20and%20Organic%20Electrolyte%20Solvents:%20A%20Comparison%20with%20Lithium,%20Sodium,%20and%20Magnesium%20Ions&rft.jtitle=Journal%20of%20the%20Electrochemical%20Society&rft.au=Okoshi,%20Masaki&rft.date=2017-01-01&rft.volume=164&rft.issue=2&rft.spage=A54&rft.epage=A60&rft.pages=A54-A60&rft.issn=0013-4651&rft.eissn=1945-7111&rft_id=info:doi/10.1149/2.0211702jes&rft_dat=%3Ciop_cross%3E0211702JES%3C/iop_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true