Boron-Doped Diamond Powder as a Durable Support for Platinum-Based Cathode Catalysts in Polymer Electrolyte Fuel Cells
Platinum nanoparticle-supported boron-doped diamond powder (Pt/BDDP) was prepared and investigated as a durable polymer electrolyte fuel cell (PEFC) cathode catalyst. The use of the nanocapsule method enabled dense deposition of Pt nanoparticles (2-5 nm in size) on a boron-doped diamond (BDD) powder...
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Veröffentlicht in: | Journal of the Electrochemical Society 2018-01, Vol.165 (6), p.F3072-F3077 |
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container_title | Journal of the Electrochemical Society |
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creator | Kondo, Takeshi Kikuchi, Mihoko Masuda, Hidetake Katsumata, Fumiya Aikawa, Tatsuo Yuasa, Makoto |
description | Platinum nanoparticle-supported boron-doped diamond powder (Pt/BDDP) was prepared and investigated as a durable polymer electrolyte fuel cell (PEFC) cathode catalyst. The use of the nanocapsule method enabled dense deposition of Pt nanoparticles (2-5 nm in size) on a boron-doped diamond (BDD) powder |
doi_str_mv | 10.1149/2.0111806jes |
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The use of the nanocapsule method enabled dense deposition of Pt nanoparticles (2-5 nm in size) on a boron-doped diamond (BDD) powder <500 nm in size. The Pt/BDDP cathode catalyst showed oxygen reduction reaction activity comparable to Pt-supported carbon black (Pt/C), indicating sufficient conductivity of the BDDP as a catalyst support. Potential cycling in a highly positive potential region (+1.0-+1.5 V vs. NHE) that simulates the start-stop operations of the PEFC was performed to investigate the durability of the Pt/BDDP catalyst. Decreases in the electrochemically active surface area of the Pt/BDDP were suppressed compared to that of Pt/C. Corrosion resistance of BDD against potential cycling was demonstrated by testing a BDD thin-film electrode. The corrosion resistance should be responsible for the improved durability of the BDDP support, possibly by lowering the Pt nanoparticle association process (e.g., agglomeration).</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/2.0111806jes</identifier><language>eng</language><publisher>The Electrochemical Society</publisher><ispartof>Journal of the Electrochemical Society, 2018-01, Vol.165 (6), p.F3072-F3077</ispartof><rights>The Author(s) 2018. 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Electrochem. Soc</addtitle><description>Platinum nanoparticle-supported boron-doped diamond powder (Pt/BDDP) was prepared and investigated as a durable polymer electrolyte fuel cell (PEFC) cathode catalyst. The use of the nanocapsule method enabled dense deposition of Pt nanoparticles (2-5 nm in size) on a boron-doped diamond (BDD) powder <500 nm in size. The Pt/BDDP cathode catalyst showed oxygen reduction reaction activity comparable to Pt-supported carbon black (Pt/C), indicating sufficient conductivity of the BDDP as a catalyst support. Potential cycling in a highly positive potential region (+1.0-+1.5 V vs. NHE) that simulates the start-stop operations of the PEFC was performed to investigate the durability of the Pt/BDDP catalyst. Decreases in the electrochemically active surface area of the Pt/BDDP were suppressed compared to that of Pt/C. Corrosion resistance of BDD against potential cycling was demonstrated by testing a BDD thin-film electrode. The corrosion resistance should be responsible for the improved durability of the BDDP support, possibly by lowering the Pt nanoparticle association process (e.g., agglomeration).</description><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><recordid>eNptkFFLwzAUhYMoOKdv_oA8-mBn0iRN--i6TYWBA_W53CYpdqRNSVpl_96MCb74dDiX7x7uPQjdUrKglBcP6YJQSnOS7U04QzNacJHIODlHM0IoS3gm6CW6CmEfLc25nKGvpfOuT1ZuMBqvWuhcr_HOfWvjMQQMeDV5qK3Bb9MwOD_ixnm8szC2_dQlSwhxrYTx02lzVLCHMAbc9jHDHroYsrZGjT6a0eDNZCwujbXhGl00YIO5-dU5-tis38vnZPv69FI-bhPFGB-T-AErMqMzpVQuCpAZ08BqpgQIARLqtFEATGREKU5J2tQy1RQ45CkQySSbo_tTrvIuBG-aavBtB_5QUVIdO6vS6q-ziN-d8NYN1d5Nvo_H_Y_-AC7wbU4</recordid><startdate>201801</startdate><enddate>201801</enddate><creator>Kondo, Takeshi</creator><creator>Kikuchi, Mihoko</creator><creator>Masuda, Hidetake</creator><creator>Katsumata, Fumiya</creator><creator>Aikawa, Tatsuo</creator><creator>Yuasa, Makoto</creator><general>The Electrochemical Society</general><scope>O3W</scope><scope>TSCCA</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4717-9012</orcidid></search><sort><creationdate>201801</creationdate><title>Boron-Doped Diamond Powder as a Durable Support for Platinum-Based Cathode Catalysts in Polymer Electrolyte Fuel Cells</title><author>Kondo, Takeshi ; Kikuchi, Mihoko ; Masuda, Hidetake ; Katsumata, Fumiya ; Aikawa, Tatsuo ; Yuasa, Makoto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-194396ed6ccc859a763da3b3c5a55a7ab2fcaa3560cc4102fb72d1a4a82a07373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kondo, Takeshi</creatorcontrib><creatorcontrib>Kikuchi, Mihoko</creatorcontrib><creatorcontrib>Masuda, Hidetake</creatorcontrib><creatorcontrib>Katsumata, Fumiya</creatorcontrib><creatorcontrib>Aikawa, Tatsuo</creatorcontrib><creatorcontrib>Yuasa, Makoto</creatorcontrib><collection>Institute of Physics Open Access Journal Titles</collection><collection>IOPscience (Open Access)</collection><collection>CrossRef</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kondo, Takeshi</au><au>Kikuchi, Mihoko</au><au>Masuda, Hidetake</au><au>Katsumata, Fumiya</au><au>Aikawa, Tatsuo</au><au>Yuasa, Makoto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Boron-Doped Diamond Powder as a Durable Support for Platinum-Based Cathode Catalysts in Polymer Electrolyte Fuel Cells</atitle><jtitle>Journal of the Electrochemical Society</jtitle><addtitle>J. Electrochem. Soc</addtitle><date>2018-01</date><risdate>2018</risdate><volume>165</volume><issue>6</issue><spage>F3072</spage><epage>F3077</epage><pages>F3072-F3077</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Platinum nanoparticle-supported boron-doped diamond powder (Pt/BDDP) was prepared and investigated as a durable polymer electrolyte fuel cell (PEFC) cathode catalyst. The use of the nanocapsule method enabled dense deposition of Pt nanoparticles (2-5 nm in size) on a boron-doped diamond (BDD) powder <500 nm in size. The Pt/BDDP cathode catalyst showed oxygen reduction reaction activity comparable to Pt-supported carbon black (Pt/C), indicating sufficient conductivity of the BDDP as a catalyst support. Potential cycling in a highly positive potential region (+1.0-+1.5 V vs. NHE) that simulates the start-stop operations of the PEFC was performed to investigate the durability of the Pt/BDDP catalyst. Decreases in the electrochemically active surface area of the Pt/BDDP were suppressed compared to that of Pt/C. Corrosion resistance of BDD against potential cycling was demonstrated by testing a BDD thin-film electrode. The corrosion resistance should be responsible for the improved durability of the BDDP support, possibly by lowering the Pt nanoparticle association process (e.g., agglomeration).</abstract><pub>The Electrochemical Society</pub><doi>10.1149/2.0111806jes</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-4717-9012</orcidid><oa>free_for_read</oa></addata></record> |
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title | Boron-Doped Diamond Powder as a Durable Support for Platinum-Based Cathode Catalysts in Polymer Electrolyte Fuel Cells |
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