Studies on Structural and Ionic Conductivity of Li2NiP2O7
Highlights Pure-phase Li 2 NiP 2 O 7 compound has been synthesized by solid-state reaction. The monoclinic-type structure with a single phase was validated by Rietveld refinement of the XRD data. The electrical properties were investigated by impedance spectroscopy technique. The frequency-dependent...
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| Veröffentlicht in: | ECS journal of solid state science and technology 2023-11, Vol.12 (11) |
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| container_title | ECS journal of solid state science and technology |
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| creator | Karray, M. Nasri, S. Mendil, R. Kammoun, I. Mahmoud, A. Oueslati, A. |
| description | Highlights Pure-phase Li 2 NiP 2 O 7 compound has been synthesized by solid-state reaction. The monoclinic-type structure with a single phase was validated by Rietveld refinement of the XRD data. The electrical properties were investigated by impedance spectroscopy technique. The frequency-dependent electrical data are analyzed in the frame-work of conductivity and electric modulus formalisms. The ion hopping mechanism controlled by the movement of Li+ cations within the Li 2 NiP 2 O 7 structure is responsible for the conduction mechanism. |
| doi_str_mv | 10.1149/2162-8777/ad0ab2 |
| format | Article |
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The monoclinic-type structure with a single phase was validated by Rietveld refinement of the XRD data. The electrical properties were investigated by impedance spectroscopy technique. The frequency-dependent electrical data are analyzed in the frame-work of conductivity and electric modulus formalisms. The ion hopping mechanism controlled by the movement of Li+ cations within the Li 2 NiP 2 O 7 structure is responsible for the conduction mechanism.</description><identifier>ISSN: 2162-8769</identifier><identifier>ISSN: 2162-8777</identifier><identifier>EISSN: 2162-8777</identifier><identifier>DOI: 10.1149/2162-8777/ad0ab2</identifier><identifier>CODEN: EJSSBG</identifier><language>eng</language><publisher>IOP Publishing</publisher><subject>Chemistry ; Chimie ; Electrical data ; Electronic, Optical and Magnetic Materials ; Frame-work ; Frequency-dependent ; Impedance spectroscopy ; Monoclinics ; Physical, chemical, mathematical & earth Sciences ; Physique, chimie, mathématiques & sciences de la terre ; Single phasis ; Solid-state reactions ; Synthesised ; Type structures ; XRD</subject><ispartof>ECS journal of solid state science and technology, 2023-11, Vol.12 (11)</ispartof><rights>2023 The Electrochemical Society (“ECS”). 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The ion hopping mechanism controlled by the movement of Li+ cations within the Li 2 NiP 2 O 7 structure is responsible for the conduction mechanism.</description><subject>Chemistry</subject><subject>Chimie</subject><subject>Electrical data</subject><subject>Electronic, Optical and Magnetic Materials</subject><subject>Frame-work</subject><subject>Frequency-dependent</subject><subject>Impedance spectroscopy</subject><subject>Monoclinics</subject><subject>Physical, chemical, mathematical & earth Sciences</subject><subject>Physique, chimie, mathématiques & sciences de la terre</subject><subject>Single phasis</subject><subject>Solid-state reactions</subject><subject>Synthesised</subject><subject>Type structures</subject><subject>XRD</subject><issn>2162-8769</issn><issn>2162-8777</issn><issn>2162-8777</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNptUE1LAzEUDKJgqb17zNGDa_OdzVGKH4Viheo5vGSzJWXZlP0o-O9NWenJx4M3DDOPYRC6p-SJUmGWjCpWlFrrJVQEHLtCswt1fcHK3KJF3x9IHlUKzdkMmd0wVjH0OLV4N3SjH8YOGgxthdepjR6vUltlNp7i8INTjTeRfcRPttV36KaGpg-LvztH368vX6v3YrN9W6-eN0XklA6FZ1zq0hhQUjsjK0mED0oR4cDLEHJ6KYGAqcHVJVEgFfHUQxCiVlA7wueIT3-bGPbBps5Fe2I2QZzw2OwteOuCZUyVljPKtciux8kV09Ee0ti1OaOlxJ77sudC7LkcO_WV5Q__yA99trBsyctJPseq5r-XgWoQ</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Karray, M.</creator><creator>Nasri, S.</creator><creator>Mendil, R.</creator><creator>Kammoun, I.</creator><creator>Mahmoud, A.</creator><creator>Oueslati, A.</creator><general>IOP Publishing</general><general>Institute of Physics</general><scope>Q33</scope><orcidid>https://orcid.org/0000-0001-8978-6641</orcidid></search><sort><creationdate>20231101</creationdate><title>Studies on Structural and Ionic Conductivity of Li2NiP2O7</title><author>Karray, M. ; Nasri, S. ; Mendil, R. ; Kammoun, I. ; Mahmoud, A. ; Oueslati, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i311t-c2357899a657b95d504ce6604bac5ee14955a0a9fabf806a560c1cae44f6afb03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chimie</topic><topic>Electrical data</topic><topic>Electronic, Optical and Magnetic Materials</topic><topic>Frame-work</topic><topic>Frequency-dependent</topic><topic>Impedance spectroscopy</topic><topic>Monoclinics</topic><topic>Physical, chemical, mathematical & earth Sciences</topic><topic>Physique, chimie, mathématiques & sciences de la terre</topic><topic>Single phasis</topic><topic>Solid-state reactions</topic><topic>Synthesised</topic><topic>Type structures</topic><topic>XRD</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karray, M.</creatorcontrib><creatorcontrib>Nasri, S.</creatorcontrib><creatorcontrib>Mendil, R.</creatorcontrib><creatorcontrib>Kammoun, I.</creatorcontrib><creatorcontrib>Mahmoud, A.</creatorcontrib><creatorcontrib>Oueslati, A.</creatorcontrib><collection>Université de Liège - Open Repository and Bibliography (ORBI)</collection><jtitle>ECS journal of solid state science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karray, M.</au><au>Nasri, S.</au><au>Mendil, R.</au><au>Kammoun, I.</au><au>Mahmoud, A.</au><au>Oueslati, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies on Structural and Ionic Conductivity of Li2NiP2O7</atitle><jtitle>ECS journal of solid state science and technology</jtitle><stitle>JSS</stitle><addtitle>ECS J. Solid State Sci. Technol</addtitle><date>2023-11-01</date><risdate>2023</risdate><volume>12</volume><issue>11</issue><issn>2162-8769</issn><issn>2162-8777</issn><eissn>2162-8777</eissn><coden>EJSSBG</coden><abstract>Highlights Pure-phase Li 2 NiP 2 O 7 compound has been synthesized by solid-state reaction. The monoclinic-type structure with a single phase was validated by Rietveld refinement of the XRD data. The electrical properties were investigated by impedance spectroscopy technique. The frequency-dependent electrical data are analyzed in the frame-work of conductivity and electric modulus formalisms. The ion hopping mechanism controlled by the movement of Li+ cations within the Li 2 NiP 2 O 7 structure is responsible for the conduction mechanism.</abstract><pub>IOP Publishing</pub><doi>10.1149/2162-8777/ad0ab2</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-8978-6641</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 2162-8769 |
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| source | IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link |
| subjects | Chemistry Chimie Electrical data Electronic, Optical and Magnetic Materials Frame-work Frequency-dependent Impedance spectroscopy Monoclinics Physical, chemical, mathematical & earth Sciences Physique, chimie, mathématiques & sciences de la terre Single phasis Solid-state reactions Synthesised Type structures XRD |
| title | Studies on Structural and Ionic Conductivity of Li2NiP2O7 |
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