Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi1/3Mn1/3Co1/3O2 Electrodes
The solvent 3-methoxytetrahydrothiophene 1, 1-dioxide (MESL) was synthesized and its cycling performances of grapshite and LiNi1/3Mn1/3Co1/3O2 (NMC) electrodes were investigated in view of the high anodic stability of MESL in the presence of lithium bis-trifluoromethanesulfonimidate (LiTFSI). Galvan...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2020-01, Vol.167 (7) |
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| creator | Flamme, Benjamin wiatowska, Jolanta Haddad, Mansour Phansavath, Phannarath Ratovelomanana-Vidal, Virginie Chagnes, Alexandre |
| description | The solvent 3-methoxytetrahydrothiophene 1, 1-dioxide (MESL) was synthesized and its cycling performances of grapshite and LiNi1/3Mn1/3Co1/3O2 (NMC) electrodes were investigated in view of the high anodic stability of MESL in the presence of lithium bis-trifluoromethanesulfonimidate (LiTFSI). Galvanostatic charge-discharge of graphite electrode was possible in MESL + LiTFSI (1 M) only in the presence of 5% (vol.) fluoroethylene carbonate (FEC) at 40 °C. On the other hand, a good cycling ability of NMC electrode with this electrolyte was observed at room temperature even at a cut-off voltage of 4.5 V vs Li+/Li. However, it was necessary to reduce the cut-off voltage from 4.5 V to 4.3 V vs Li+/Li in order to keep a good cycling ability |
| doi_str_mv | 10.1149/1945-7111/ab63c3 |
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Galvanostatic charge-discharge of graphite electrode was possible in MESL + LiTFSI (1 M) only in the presence of 5% (vol.) fluoroethylene carbonate (FEC) at 40 °C. On the other hand, a good cycling ability of NMC electrode with this electrolyte was observed at room temperature even at a cut-off voltage of 4.5 V vs Li+/Li. However, it was necessary to reduce the cut-off voltage from 4.5 V to 4.3 V vs Li+/Li in order to keep a good cycling ability <<< when the temperature was increased from 25 °C to 40 °C due to an exaltation of oxidation reactions onto the cathode surface. X-Ray Photoelectron Spectroscopy (XPS) analyses were performed to investigate the electrode/electrolyte interphase and formation of passive layer on the electrode surfaces in order to explain the differences of cycling ability of NMC and graphite electrodes at room temperature and 40 °C.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1945-7111/ab63c3</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>IOP Publishing</publisher><ispartof>Journal of the Electrochemical Society, 2020-01, Vol.167 (7)</ispartof><rights>2020 The Author(s). 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Electrochem. Soc</addtitle><description>The solvent 3-methoxytetrahydrothiophene 1, 1-dioxide (MESL) was synthesized and its cycling performances of grapshite and LiNi1/3Mn1/3Co1/3O2 (NMC) electrodes were investigated in view of the high anodic stability of MESL in the presence of lithium bis-trifluoromethanesulfonimidate (LiTFSI). Galvanostatic charge-discharge of graphite electrode was possible in MESL + LiTFSI (1 M) only in the presence of 5% (vol.) fluoroethylene carbonate (FEC) at 40 °C. On the other hand, a good cycling ability of NMC electrode with this electrolyte was observed at room temperature even at a cut-off voltage of 4.5 V vs Li+/Li. However, it was necessary to reduce the cut-off voltage from 4.5 V to 4.3 V vs Li+/Li in order to keep a good cycling ability <<< when the temperature was increased from 25 °C to 40 °C due to an exaltation of oxidation reactions onto the cathode surface. X-Ray Photoelectron Spectroscopy (XPS) analyses were performed to investigate the electrode/electrolyte interphase and formation of passive layer on the electrode surfaces in order to explain the differences of cycling ability of NMC and graphite electrodes at room temperature and 40 °C.</description><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><recordid>eNptkE1PwzAMhiMEEmNw55gjB8oc0q9wg2mMSYUNAefISxOWqWunJkXqL-HvkrGJExdbth77lR5CLhncMBaLERNxEmWMsREuU674ERn8rY7JAIDxKE4TdkrOnFuHkeVxNiDfb11lmlrTB3S6jCaVVr5tqt5rR03T0sL6le020aypA-K9bq12d3Tcq8rWn3Sh20BtsFaBx7qkC3TOfqG3gS-w1y197bCyvqeNodMWtyvr9S9Z2BfLRvy5DmXchDK_pYf4UrtzcmKwcvri0Ifk43HyPn6Kivl0Nr4vIss59xEuhVAmLVExjbkoQYMBkUGsRRoLUEzlOmE5ZAmWClgqDCYKEWKM0ywH4ENyvf9rm61cN11bhzTJQO6kyp1BuTMo91IDfvUPvtbhJM1kJiGDBHK5LQ3_AbVheQM</recordid><startdate>20200110</startdate><enddate>20200110</enddate><creator>Flamme, Benjamin</creator><creator>wiatowska, Jolanta</creator><creator>Haddad, Mansour</creator><creator>Phansavath, Phannarath</creator><creator>Ratovelomanana-Vidal, Virginie</creator><creator>Chagnes, Alexandre</creator><general>IOP Publishing</general><scope>O3W</scope><scope>TSCCA</scope></search><sort><creationdate>20200110</creationdate><title>Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi1/3Mn1/3Co1/3O2 Electrodes</title><author>Flamme, Benjamin ; wiatowska, Jolanta ; Haddad, Mansour ; Phansavath, Phannarath ; Ratovelomanana-Vidal, Virginie ; Chagnes, Alexandre</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i333t-ab99cf6dac1ea89d0e0f09704e96490c1c8e518075adc0169fa5caa04a4678003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Flamme, Benjamin</creatorcontrib><creatorcontrib>wiatowska, Jolanta</creatorcontrib><creatorcontrib>Haddad, Mansour</creatorcontrib><creatorcontrib>Phansavath, Phannarath</creatorcontrib><creatorcontrib>Ratovelomanana-Vidal, Virginie</creatorcontrib><creatorcontrib>Chagnes, Alexandre</creatorcontrib><collection>IOP Publishing Free Content</collection><collection>IOPscience (Open Access)</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Flamme, Benjamin</au><au>wiatowska, Jolanta</au><au>Haddad, Mansour</au><au>Phansavath, Phannarath</au><au>Ratovelomanana-Vidal, Virginie</au><au>Chagnes, Alexandre</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi1/3Mn1/3Co1/3O2 Electrodes</atitle><jtitle>Journal of the Electrochemical Society</jtitle><stitle>JES</stitle><addtitle>J. Electrochem. Soc</addtitle><date>2020-01-10</date><risdate>2020</risdate><volume>167</volume><issue>7</issue><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>The solvent 3-methoxytetrahydrothiophene 1, 1-dioxide (MESL) was synthesized and its cycling performances of grapshite and LiNi1/3Mn1/3Co1/3O2 (NMC) electrodes were investigated in view of the high anodic stability of MESL in the presence of lithium bis-trifluoromethanesulfonimidate (LiTFSI). Galvanostatic charge-discharge of graphite electrode was possible in MESL + LiTFSI (1 M) only in the presence of 5% (vol.) fluoroethylene carbonate (FEC) at 40 °C. On the other hand, a good cycling ability of NMC electrode with this electrolyte was observed at room temperature even at a cut-off voltage of 4.5 V vs Li+/Li. However, it was necessary to reduce the cut-off voltage from 4.5 V to 4.3 V vs Li+/Li in order to keep a good cycling ability <<< when the temperature was increased from 25 °C to 40 °C due to an exaltation of oxidation reactions onto the cathode surface. X-Ray Photoelectron Spectroscopy (XPS) analyses were performed to investigate the electrode/electrolyte interphase and formation of passive layer on the electrode surfaces in order to explain the differences of cycling ability of NMC and graphite electrodes at room temperature and 40 °C.</abstract><pub>IOP Publishing</pub><doi>10.1149/1945-7111/ab63c3</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| title | Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi1/3Mn1/3Co1/3O2 Electrodes |
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