Effect of 2,2,6,6-Tetramethylpiperidinyl-Oxide (TEMPO) as an Electrolyte Additive and its SEI Formation on MCMB-Electrode

Effect of 2,2,6,6-Tetramethylpiperidinyl-Oxide (TEMPO) as an Electrolyte Additive and its SEI Formation on MCMB-Electrode

In this study, we developed the benefit of TEMPO additive for the suppression of the solvent/additive decomposition by trapping the radicals formed. With unusual stability as a neutral radical the 2 % TEMPO as an additive into STD + 5% FEC electrolyte resulted in the modification of the interphase....

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Veröffentlicht in:ECS transactions 2020-06, Vol.97 (7), p.135-142
Hauptverfasser: Lin, Shawn D., Yohannes, Yonas Beyene, Hwang, Bing-Joe, Wu, Nae-Lih
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creator Lin, Shawn D.
Yohannes, Yonas Beyene
Hwang, Bing-Joe
Wu, Nae-Lih
description In this study, we developed the benefit of TEMPO additive for the suppression of the solvent/additive decomposition by trapping the radicals formed. With unusual stability as a neutral radical the 2 % TEMPO as an additive into STD + 5% FEC electrolyte resulted in the modification of the interphase. Through in-situ DRIFTS results we can find out and investigate the mechanism for the decomposition of TEMPO. The studies described herein also demonstrate that MCMB-electrodes in STD + 5% FEC solution containing TEMPO additive can be utilized together with high voltage cathode.
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title Effect of 2,2,6,6-Tetramethylpiperidinyl-Oxide (TEMPO) as an Electrolyte Additive and its SEI Formation on MCMB-Electrode
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