Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment

Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment

New original a direct borohydrid fuel cell divided by bipolar membrane with H2O2 co-generation was development. It was established that application of bipolar membrane enables to keep constant pH in catholyte within 2.5-3.2 limits, which allowed us to carry out treatment of water polluted by organic...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ECS transactions 2014-08, Vol.59 (1), p.479-493
Hauptverfasser: Nikoleishvili, Paata, Kveselava, Valentina, Tsutsumia, Gigla, Gorelishvili, Giorgi, Kurtanidze, Rusudan, Sharabidze, Daviti
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 493
container_issue 1
container_start_page 479
container_title ECS transactions
container_volume 59
creator Nikoleishvili, Paata
Kveselava, Valentina
Tsutsumia, Gigla
Gorelishvili, Giorgi
Kurtanidze, Rusudan
Sharabidze, Daviti
description New original a direct borohydrid fuel cell divided by bipolar membrane with H2O2 co-generation was development. It was established that application of bipolar membrane enables to keep constant pH in catholyte within 2.5-3.2 limits, which allowed us to carry out treatment of water polluted by organic compounds in fuel cell catholyte by electro-Fenton and photo-electro-Fenton methods. The electromotive force of borohydrid fuel cell is 1.1 V. Most efficient methods was photo-electro-Fenton, which enabled to decrease COD (start COD = 500 ppm) of catholytes containing phenol, valsaren, BI-58 and valsaciper to 30, 11, 9 and 3 ppm, correspondingly after 180 min treatment. At the increase of catholyte temperature from 200C to 400C in the same period phenol COD fell to 5 ppm.
doi_str_mv 10.1149/05901.0479ecst
format Article
fullrecord <record><control><sourceid>iop_cross</sourceid><recordid>TN_cdi_iop_journals_10_1149_05901_0479ecst</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10.1149/05901.0479ecst</sourcerecordid><originalsourceid>FETCH-LOGICAL-c226t-7402e9e980027ded070594c9f8f438f137e7fe11f28b78582415abe958a3015a3</originalsourceid><addsrcrecordid>eNp1kD1PwzAQhi0EEqWwMntGSrCdD9sjDRSQgliKGCMnOaupkjg6u0L99wRaRpa7d7jn9Ooh5JazmPNU37NMMx6zVGpofDgjC64TFeUykeennKlcXJIr73eM5TMjF6R87BCaQFcO3fbQYtcCXe-hpwX0Pf3qwpauusn1BukbDDWaEah1SD-NDzDPAEg3CCYMMIZrcmFN7-HmtJfkY_20KV6i8v35tXgoo0aIPEQyZQI0aMWYkC20TM7V00ZbZdNEWZ5IkBY4t0LVUmVKpDwzNehMmYTNMVmS-Pi3Qec9gq0m7AaDh4qz6sdF9eui-nMxA3dHoHNTtXN7HOd6_x1_A-ApXxg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment</title><source>IOP Publishing Journals</source><source>Institute of Physics (IOP) Journals - HEAL-Link</source><creator>Nikoleishvili, Paata ; Kveselava, Valentina ; Tsutsumia, Gigla ; Gorelishvili, Giorgi ; Kurtanidze, Rusudan ; Sharabidze, Daviti</creator><creatorcontrib>Nikoleishvili, Paata ; Kveselava, Valentina ; Tsutsumia, Gigla ; Gorelishvili, Giorgi ; Kurtanidze, Rusudan ; Sharabidze, Daviti</creatorcontrib><description>New original a direct borohydrid fuel cell divided by bipolar membrane with H2O2 co-generation was development. It was established that application of bipolar membrane enables to keep constant pH in catholyte within 2.5-3.2 limits, which allowed us to carry out treatment of water polluted by organic compounds in fuel cell catholyte by electro-Fenton and photo-electro-Fenton methods. The electromotive force of borohydrid fuel cell is 1.1 V. Most efficient methods was photo-electro-Fenton, which enabled to decrease COD (start COD = 500 ppm) of catholytes containing phenol, valsaren, BI-58 and valsaciper to 30, 11, 9 and 3 ppm, correspondingly after 180 min treatment. At the increase of catholyte temperature from 200C to 400C in the same period phenol COD fell to 5 ppm.</description><identifier>ISSN: 1938-5862</identifier><identifier>EISSN: 1938-6737</identifier><identifier>DOI: 10.1149/05901.0479ecst</identifier><language>eng</language><publisher>The Electrochemical Society, Inc</publisher><ispartof>ECS transactions, 2014-08, Vol.59 (1), p.479-493</ispartof><rights>2014 ECS - The Electrochemical Society</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c226t-7402e9e980027ded070594c9f8f438f137e7fe11f28b78582415abe958a3015a3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1149/05901.0479ecst/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,53846,53893</link.rule.ids></links><search><creatorcontrib>Nikoleishvili, Paata</creatorcontrib><creatorcontrib>Kveselava, Valentina</creatorcontrib><creatorcontrib>Tsutsumia, Gigla</creatorcontrib><creatorcontrib>Gorelishvili, Giorgi</creatorcontrib><creatorcontrib>Kurtanidze, Rusudan</creatorcontrib><creatorcontrib>Sharabidze, Daviti</creatorcontrib><title>Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment</title><title>ECS transactions</title><addtitle>ECS Trans</addtitle><description>New original a direct borohydrid fuel cell divided by bipolar membrane with H2O2 co-generation was development. It was established that application of bipolar membrane enables to keep constant pH in catholyte within 2.5-3.2 limits, which allowed us to carry out treatment of water polluted by organic compounds in fuel cell catholyte by electro-Fenton and photo-electro-Fenton methods. The electromotive force of borohydrid fuel cell is 1.1 V. Most efficient methods was photo-electro-Fenton, which enabled to decrease COD (start COD = 500 ppm) of catholytes containing phenol, valsaren, BI-58 and valsaciper to 30, 11, 9 and 3 ppm, correspondingly after 180 min treatment. At the increase of catholyte temperature from 200C to 400C in the same period phenol COD fell to 5 ppm.</description><issn>1938-5862</issn><issn>1938-6737</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAQhi0EEqWwMntGSrCdD9sjDRSQgliKGCMnOaupkjg6u0L99wRaRpa7d7jn9Ooh5JazmPNU37NMMx6zVGpofDgjC64TFeUykeennKlcXJIr73eM5TMjF6R87BCaQFcO3fbQYtcCXe-hpwX0Pf3qwpauusn1BukbDDWaEah1SD-NDzDPAEg3CCYMMIZrcmFN7-HmtJfkY_20KV6i8v35tXgoo0aIPEQyZQI0aMWYkC20TM7V00ZbZdNEWZ5IkBY4t0LVUmVKpDwzNehMmYTNMVmS-Pi3Qec9gq0m7AaDh4qz6sdF9eui-nMxA3dHoHNTtXN7HOd6_x1_A-ApXxg</recordid><startdate>20140820</startdate><enddate>20140820</enddate><creator>Nikoleishvili, Paata</creator><creator>Kveselava, Valentina</creator><creator>Tsutsumia, Gigla</creator><creator>Gorelishvili, Giorgi</creator><creator>Kurtanidze, Rusudan</creator><creator>Sharabidze, Daviti</creator><general>The Electrochemical Society, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20140820</creationdate><title>Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment</title><author>Nikoleishvili, Paata ; Kveselava, Valentina ; Tsutsumia, Gigla ; Gorelishvili, Giorgi ; Kurtanidze, Rusudan ; Sharabidze, Daviti</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-7402e9e980027ded070594c9f8f438f137e7fe11f28b78582415abe958a3015a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Nikoleishvili, Paata</creatorcontrib><creatorcontrib>Kveselava, Valentina</creatorcontrib><creatorcontrib>Tsutsumia, Gigla</creatorcontrib><creatorcontrib>Gorelishvili, Giorgi</creatorcontrib><creatorcontrib>Kurtanidze, Rusudan</creatorcontrib><creatorcontrib>Sharabidze, Daviti</creatorcontrib><collection>CrossRef</collection><jtitle>ECS transactions</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nikoleishvili, Paata</au><au>Kveselava, Valentina</au><au>Tsutsumia, Gigla</au><au>Gorelishvili, Giorgi</au><au>Kurtanidze, Rusudan</au><au>Sharabidze, Daviti</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment</atitle><jtitle>ECS transactions</jtitle><addtitle>ECS Trans</addtitle><date>2014-08-20</date><risdate>2014</risdate><volume>59</volume><issue>1</issue><spage>479</spage><epage>493</epage><pages>479-493</pages><issn>1938-5862</issn><eissn>1938-6737</eissn><abstract>New original a direct borohydrid fuel cell divided by bipolar membrane with H2O2 co-generation was development. It was established that application of bipolar membrane enables to keep constant pH in catholyte within 2.5-3.2 limits, which allowed us to carry out treatment of water polluted by organic compounds in fuel cell catholyte by electro-Fenton and photo-electro-Fenton methods. The electromotive force of borohydrid fuel cell is 1.1 V. Most efficient methods was photo-electro-Fenton, which enabled to decrease COD (start COD = 500 ppm) of catholytes containing phenol, valsaren, BI-58 and valsaciper to 30, 11, 9 and 3 ppm, correspondingly after 180 min treatment. At the increase of catholyte temperature from 200C to 400C in the same period phenol COD fell to 5 ppm.</abstract><pub>The Electrochemical Society, Inc</pub><doi>10.1149/05901.0479ecst</doi><tpages>15</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1938-5862
ispartof ECS transactions, 2014-08, Vol.59 (1), p.479-493
issn 1938-5862
1938-6737
language eng
recordid cdi_iop_journals_10_1149_05901_0479ecst
source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
title Direct Borohydride Fuel Cell with Bipolar Membrane for Waste Water Treatment
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T16%3A25%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-iop_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Direct%20Borohydride%20Fuel%20Cell%20with%20Bipolar%20Membrane%20for%20Waste%20Water%20Treatment&rft.jtitle=ECS%20transactions&rft.au=Nikoleishvili,%20Paata&rft.date=2014-08-20&rft.volume=59&rft.issue=1&rft.spage=479&rft.epage=493&rft.pages=479-493&rft.issn=1938-5862&rft.eissn=1938-6737&rft_id=info:doi/10.1149/05901.0479ecst&rft_dat=%3Ciop_cross%3E10.1149/05901.0479ecst%3C/iop_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true