Strong chiral optical force for small chiral molecules based on electric-dipole interactions, inspired by the asymmetrical hydrozoan Velella velella
Drawing inspiration from a remarkable chiral force found in nature, we show that a static electric field combined with an optical lin ⊥ lin polarization standing wave can exert a chiral optical force on a small chiral molecule that is several orders of magnitude stronger than other chiral optical fo...
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| Veröffentlicht in: | New journal of physics 2023-08, Vol.25 (8), p.83006 |
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| container_title | New journal of physics |
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| creator | Cameron, Robert P McArthur, Duncan Yao, Alison M |
| description | Drawing inspiration from a remarkable chiral force found in nature, we show that a static electric field combined with an optical lin
⊥
lin polarization standing wave can exert a chiral optical force on a small chiral molecule that is several orders of magnitude stronger than other chiral optical forces proposed to date, being based on leading electric-dipole interactions rather than relying on weak magnetic-dipole and electric-quadrupole interactions. Our chiral optical force applies to most small chiral molecules, including isotopically chiral molecules, and does not require a specific energy-level structure. Potential applications range from chiral molecular matter-wave interferometry for precision metrology and tests of fundamental physics to the resolution of enantiomers for use in chemistry and biology. |
| doi_str_mv | 10.1088/1367-2630/ace7ee |
| format | Article |
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| subjects | chiral resolution chirality chiroptics Dipole interactions Electric fields Enantiomers Interferometry isotopic chirality matter-wave interferometry Molecular structure optical forces Physics Quadrupole interaction Quadrupoles Specific energy Standing waves |
| title | Strong chiral optical force for small chiral molecules based on electric-dipole interactions, inspired by the asymmetrical hydrozoan Velella velella |
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