Electrochemical Detection of Eugenol (EU) Using Polyacrylonitrile Molecular Imprinted Polymer Embedded Graphite (PAN-MIP/G) Electrode
In this paper, development of a polyacrylonitrile molecularly imprinted polymer embedded graphite (PANMIP/G) electrode is described and its use as a sensitive and selective electrochemical sensor for determination of Eugenol (EU) in various food ingredients. The pure polyacrylonitrile is found to be...
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| Veröffentlicht in: | IEEE sensors journal 2020-01, Vol.20 (1), p.39-46 |
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| creator | Naskar, Hemanta Ghatak, Barnali Biswas, Sudip Singh, Prabal Pratap Tudu, Bipan Bandyopadhyay, Rajib |
| description | In this paper, development of a polyacrylonitrile molecularly imprinted polymer embedded graphite (PANMIP/G) electrode is described and its use as a sensitive and selective electrochemical sensor for determination of Eugenol (EU) in various food ingredients. The pure polyacrylonitrile is found to be the most efficient polymer material in comparison with other compositions involving acrylo-acid, acrylamide, acrylate esters and their mixtures. The PAN-MIP/G electrode shows three different linear determination ranges: 0.0005-1.0 μ, 1-50 μ and 50-160 μ with lowest detection limit of 0.0004 μM. PAN-MIP/G is characterized by field emission scanning electron microscope (FESEM) and fourier transform infra-red (FTIR) spectroscopy. The effect of variables such as electrolytes, pH and scan rate are optimized to get highest sensitivity. The PAN-MIP/G electrode shows good repeatability, reproducibility and excellent sensitivity towards EU. The effects of common interferences on the EU peak current are studied. Furthermore, the developed electrode is successfully applied for the determination of EU in curry powder, clove powder and capsule samples. |
| doi_str_mv | 10.1109/JSEN.2019.2941637 |
| format | Article |
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The pure polyacrylonitrile is found to be the most efficient polymer material in comparison with other compositions involving acrylo-acid, acrylamide, acrylate esters and their mixtures. The PAN-MIP/G electrode shows three different linear determination ranges: 0.0005-1.0 μ, 1-50 μ and 50-160 μ with lowest detection limit of 0.0004 μM. PAN-MIP/G is characterized by field emission scanning electron microscope (FESEM) and fourier transform infra-red (FTIR) spectroscopy. The effect of variables such as electrolytes, pH and scan rate are optimized to get highest sensitivity. The PAN-MIP/G electrode shows good repeatability, reproducibility and excellent sensitivity towards EU. The effects of common interferences on the EU peak current are studied. Furthermore, the developed electrode is successfully applied for the determination of EU in curry powder, clove powder and capsule samples.</description><identifier>ISSN: 1530-437X</identifier><identifier>EISSN: 1558-1748</identifier><identifier>DOI: 10.1109/JSEN.2019.2941637</identifier><identifier>CODEN: ISJEAZ</identifier><language>eng</language><publisher>New York: IEEE</publisher><subject>Acrylamide ; Chemical sensors ; differential pulse voltammetry ; Electrochemical analysis ; Electrodes ; Electrolytes ; Esters ; Ethanol ; eugenol ; Field emission microscopy ; Fourier transforms ; Graphite ; Imprinted polymers ; Molecular imprinted polymer ; nano molar detection ; Polyacrylonitrile ; Polymers ; Powders ; Reproducibility ; Sensitivity ; Sensors ; spice powder ; Surface morphology</subject><ispartof>IEEE sensors journal, 2020-01, Vol.20 (1), p.39-46</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. (IEEE) 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c293t-27288682842a81c7fb7c1d6e5b78125e43474815c0a58da659e28259370158743</citedby><cites>FETCH-LOGICAL-c293t-27288682842a81c7fb7c1d6e5b78125e43474815c0a58da659e28259370158743</cites><orcidid>0000-0002-3836-6222 ; 0000-0002-9513-3337</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/8839100$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>314,776,780,792,27901,27902,54733</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/8839100$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Naskar, Hemanta</creatorcontrib><creatorcontrib>Ghatak, Barnali</creatorcontrib><creatorcontrib>Biswas, Sudip</creatorcontrib><creatorcontrib>Singh, Prabal Pratap</creatorcontrib><creatorcontrib>Tudu, Bipan</creatorcontrib><creatorcontrib>Bandyopadhyay, Rajib</creatorcontrib><title>Electrochemical Detection of Eugenol (EU) Using Polyacrylonitrile Molecular Imprinted Polymer Embedded Graphite (PAN-MIP/G) Electrode</title><title>IEEE sensors journal</title><addtitle>JSEN</addtitle><description>In this paper, development of a polyacrylonitrile molecularly imprinted polymer embedded graphite (PANMIP/G) electrode is described and its use as a sensitive and selective electrochemical sensor for determination of Eugenol (EU) in various food ingredients. The pure polyacrylonitrile is found to be the most efficient polymer material in comparison with other compositions involving acrylo-acid, acrylamide, acrylate esters and their mixtures. The PAN-MIP/G electrode shows three different linear determination ranges: 0.0005-1.0 μ, 1-50 μ and 50-160 μ with lowest detection limit of 0.0004 μM. PAN-MIP/G is characterized by field emission scanning electron microscope (FESEM) and fourier transform infra-red (FTIR) spectroscopy. The effect of variables such as electrolytes, pH and scan rate are optimized to get highest sensitivity. The PAN-MIP/G electrode shows good repeatability, reproducibility and excellent sensitivity towards EU. The effects of common interferences on the EU peak current are studied. Furthermore, the developed electrode is successfully applied for the determination of EU in curry powder, clove powder and capsule samples.</description><subject>Acrylamide</subject><subject>Chemical sensors</subject><subject>differential pulse voltammetry</subject><subject>Electrochemical analysis</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Esters</subject><subject>Ethanol</subject><subject>eugenol</subject><subject>Field emission microscopy</subject><subject>Fourier transforms</subject><subject>Graphite</subject><subject>Imprinted polymers</subject><subject>Molecular imprinted polymer</subject><subject>nano molar detection</subject><subject>Polyacrylonitrile</subject><subject>Polymers</subject><subject>Powders</subject><subject>Reproducibility</subject><subject>Sensitivity</subject><subject>Sensors</subject><subject>spice powder</subject><subject>Surface morphology</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNo9kM1OwkAUhRujiYg-gHEziRtYFOen05lZEqyIASRREnfNML1ASdvBaVnwAL63UyGu7s3Jd-_JOUFwT_CAEKye3j6S-YBiogZURSRm4iLoEM5lSEQkL9ud4TBi4us6uKnrHfak4KIT_CQFmMZZs4UyN7pAz9B4IbcVsmuUHDZQ2QL1kmUfLeu82qCFLY7auGNhq7xxeQFoZv2LQ6EdmpR7l1cNZH9UCQ4l5QqyzAtjp_fbvAHUWwzn4WyyeBr30dk7g9vgaq2LGu7OsxssX5LP0Ws4fR9PRsNpaKhiTUgFlTKWVEZUS2LEeiUMyWLgKyEJ5RCxyKcl3GDNZaZjroBKyhUTmHApItYNHk9_985-H6Bu0p09uMpbppQxxpmKlfAUOVHG2bp2sE59rFK7Y0pw2radtm2nbdvpuW1_83C6yQHgn5eSKYIx-wX3PnoF</recordid><startdate>20200101</startdate><enddate>20200101</enddate><creator>Naskar, Hemanta</creator><creator>Ghatak, Barnali</creator><creator>Biswas, Sudip</creator><creator>Singh, Prabal Pratap</creator><creator>Tudu, Bipan</creator><creator>Bandyopadhyay, Rajib</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. (IEEE)</general><scope>97E</scope><scope>RIA</scope><scope>RIE</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3836-6222</orcidid><orcidid>https://orcid.org/0000-0002-9513-3337</orcidid></search><sort><creationdate>20200101</creationdate><title>Electrochemical Detection of Eugenol (EU) Using Polyacrylonitrile Molecular Imprinted Polymer Embedded Graphite (PAN-MIP/G) Electrode</title><author>Naskar, Hemanta ; Ghatak, Barnali ; Biswas, Sudip ; Singh, Prabal Pratap ; Tudu, Bipan ; Bandyopadhyay, Rajib</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-27288682842a81c7fb7c1d6e5b78125e43474815c0a58da659e28259370158743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acrylamide</topic><topic>Chemical sensors</topic><topic>differential pulse voltammetry</topic><topic>Electrochemical analysis</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Esters</topic><topic>Ethanol</topic><topic>eugenol</topic><topic>Field emission microscopy</topic><topic>Fourier transforms</topic><topic>Graphite</topic><topic>Imprinted polymers</topic><topic>Molecular imprinted polymer</topic><topic>nano molar detection</topic><topic>Polyacrylonitrile</topic><topic>Polymers</topic><topic>Powders</topic><topic>Reproducibility</topic><topic>Sensitivity</topic><topic>Sensors</topic><topic>spice powder</topic><topic>Surface morphology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Naskar, Hemanta</creatorcontrib><creatorcontrib>Ghatak, Barnali</creatorcontrib><creatorcontrib>Biswas, Sudip</creatorcontrib><creatorcontrib>Singh, Prabal Pratap</creatorcontrib><creatorcontrib>Tudu, Bipan</creatorcontrib><creatorcontrib>Bandyopadhyay, Rajib</creatorcontrib><collection>IEEE All-Society Periodicals Package (ASPP) 2005-present</collection><collection>IEEE All-Society Periodicals Package (ASPP) 1998-Present</collection><collection>IEEE Electronic Library (IEL)</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>IEEE sensors journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Naskar, Hemanta</au><au>Ghatak, Barnali</au><au>Biswas, Sudip</au><au>Singh, Prabal Pratap</au><au>Tudu, Bipan</au><au>Bandyopadhyay, Rajib</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical Detection of Eugenol (EU) Using Polyacrylonitrile Molecular Imprinted Polymer Embedded Graphite (PAN-MIP/G) Electrode</atitle><jtitle>IEEE sensors journal</jtitle><stitle>JSEN</stitle><date>2020-01-01</date><risdate>2020</risdate><volume>20</volume><issue>1</issue><spage>39</spage><epage>46</epage><pages>39-46</pages><issn>1530-437X</issn><eissn>1558-1748</eissn><coden>ISJEAZ</coden><abstract>In this paper, development of a polyacrylonitrile molecularly imprinted polymer embedded graphite (PANMIP/G) electrode is described and its use as a sensitive and selective electrochemical sensor for determination of Eugenol (EU) in various food ingredients. The pure polyacrylonitrile is found to be the most efficient polymer material in comparison with other compositions involving acrylo-acid, acrylamide, acrylate esters and their mixtures. The PAN-MIP/G electrode shows three different linear determination ranges: 0.0005-1.0 μ, 1-50 μ and 50-160 μ with lowest detection limit of 0.0004 μM. PAN-MIP/G is characterized by field emission scanning electron microscope (FESEM) and fourier transform infra-red (FTIR) spectroscopy. The effect of variables such as electrolytes, pH and scan rate are optimized to get highest sensitivity. The PAN-MIP/G electrode shows good repeatability, reproducibility and excellent sensitivity towards EU. The effects of common interferences on the EU peak current are studied. Furthermore, the developed electrode is successfully applied for the determination of EU in curry powder, clove powder and capsule samples.</abstract><cop>New York</cop><pub>IEEE</pub><doi>10.1109/JSEN.2019.2941637</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3836-6222</orcidid><orcidid>https://orcid.org/0000-0002-9513-3337</orcidid></addata></record> |
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| subjects | Acrylamide Chemical sensors differential pulse voltammetry Electrochemical analysis Electrodes Electrolytes Esters Ethanol eugenol Field emission microscopy Fourier transforms Graphite Imprinted polymers Molecular imprinted polymer nano molar detection Polyacrylonitrile Polymers Powders Reproducibility Sensitivity Sensors spice powder Surface morphology |
| title | Electrochemical Detection of Eugenol (EU) Using Polyacrylonitrile Molecular Imprinted Polymer Embedded Graphite (PAN-MIP/G) Electrode |
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