Fabrication of Au-Decorated 3D ZnO Nanostructures as Recyclable SERS Substrates
Highly roughened Au-decorated 3D ZnO nano-structures were prepared using a combination of prism holographic lithography and atomic layer deposition techniques. Prism holographic lithography is a simple and rapid method for fabricating ordered 3D nanostructures using the optical interference effects...
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Veröffentlicht in: | IEEE sensors journal 2016-05, Vol.16 (10), p.3382-3386 |
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creator | Park, Sung-Gyu Jeon, Tae Yoon Jeon, Hwan Chul Kwon, Jung-Dae Mun, ChaeWon Lee, MinKyoung Cho, Byungjin Kim, Chang Su Song, Myungkwan Kim, Dong-Ho |
description | Highly roughened Au-decorated 3D ZnO nano-structures were prepared using a combination of prism holographic lithography and atomic layer deposition techniques. Prism holographic lithography is a simple and rapid method for fabricating ordered 3D nanostructures using the optical interference effects of multiple beams derived from a specially designed prism. Highly ordered reproducible surface-enhanced Raman scattering (SERS) substrates are needed for the reliable calibration of target analyte concentrations. A high density of Au nanoparticles separated by nanoscale gaps was generated on the Au-coated ZnO inverse structures. The nanogaps may function as strong hot spots for highly sensitive SERS-based chemical/biological sensors. The optimized SERS intensity from the prepared Au-coated 3D ZnO inverse structures was 20 times the intensity obtained from an Au-coated flat glass control substrate. The surfaces could be reused after the photocatalytic degradation and removal of adsorbates in the presence of ZnO. The Au-coated 3D ZnO structures described here offer an alternative to traditional single-use SERS substrates. |
doi_str_mv | 10.1109/JSEN.2015.2418787 |
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Prism holographic lithography is a simple and rapid method for fabricating ordered 3D nanostructures using the optical interference effects of multiple beams derived from a specially designed prism. Highly ordered reproducible surface-enhanced Raman scattering (SERS) substrates are needed for the reliable calibration of target analyte concentrations. A high density of Au nanoparticles separated by nanoscale gaps was generated on the Au-coated ZnO inverse structures. The nanogaps may function as strong hot spots for highly sensitive SERS-based chemical/biological sensors. The optimized SERS intensity from the prepared Au-coated 3D ZnO inverse structures was 20 times the intensity obtained from an Au-coated flat glass control substrate. The surfaces could be reused after the photocatalytic degradation and removal of adsorbates in the presence of ZnO. 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Prism holographic lithography is a simple and rapid method for fabricating ordered 3D nanostructures using the optical interference effects of multiple beams derived from a specially designed prism. Highly ordered reproducible surface-enhanced Raman scattering (SERS) substrates are needed for the reliable calibration of target analyte concentrations. A high density of Au nanoparticles separated by nanoscale gaps was generated on the Au-coated ZnO inverse structures. The nanogaps may function as strong hot spots for highly sensitive SERS-based chemical/biological sensors. The optimized SERS intensity from the prepared Au-coated 3D ZnO inverse structures was 20 times the intensity obtained from an Au-coated flat glass control substrate. The surfaces could be reused after the photocatalytic degradation and removal of adsorbates in the presence of ZnO. The Au-coated 3D ZnO structures described here offer an alternative to traditional single-use SERS substrates.</description><subject>3D nanostructures</subject><subject>atomic layer deposition</subject><subject>Gold</subject><subject>nanoscale gaps</subject><subject>Nanostructures</subject><subject>Photovoltaic cells</subject><subject>prism holographic lithography</subject><subject>Rough surfaces</subject><subject>SERS substrates</subject><subject>Substrates</subject><subject>Surface treatment</subject><subject>Three-dimensional displays</subject><subject>Zinc oxide</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNo9kMlqwzAQhkVpoWnaByi9CHp2KlmrjyFLF0ICcQulFyHLI3BI7VSyD3n72CT0NHP4_lk-hB4pmVBKspePfLGepISKScqpVlpdoREVQidUcX099IwknKnvW3QX444QmimhRmiztEWonG2rpsaNx9MumYNrgm2hxGyOf-oNXtu6iW3oXNsFiNhGvAV3dHtb7AHni22O867ogT4T79GNt_sID5c6Rl_LxefsLVltXt9n01Xi0oy1SWaZlNDf6xxXxDPpUymc0Io7XnIFpS9Sy4sSnCw0T7kqmSLaStCeZJlWbIyez3MPofnrILZm13Sh7lca2n9PacaF6Cl6plxoYgzgzSFUvzYcDSVm8GYGb2bwZi7e-szTOVMBwD-viJKSMHYCxYZoMQ</recordid><startdate>20160515</startdate><enddate>20160515</enddate><creator>Park, Sung-Gyu</creator><creator>Jeon, Tae Yoon</creator><creator>Jeon, Hwan Chul</creator><creator>Kwon, Jung-Dae</creator><creator>Mun, ChaeWon</creator><creator>Lee, MinKyoung</creator><creator>Cho, Byungjin</creator><creator>Kim, Chang Su</creator><creator>Song, Myungkwan</creator><creator>Kim, Dong-Ho</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. 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Prism holographic lithography is a simple and rapid method for fabricating ordered 3D nanostructures using the optical interference effects of multiple beams derived from a specially designed prism. Highly ordered reproducible surface-enhanced Raman scattering (SERS) substrates are needed for the reliable calibration of target analyte concentrations. A high density of Au nanoparticles separated by nanoscale gaps was generated on the Au-coated ZnO inverse structures. The nanogaps may function as strong hot spots for highly sensitive SERS-based chemical/biological sensors. The optimized SERS intensity from the prepared Au-coated 3D ZnO inverse structures was 20 times the intensity obtained from an Au-coated flat glass control substrate. The surfaces could be reused after the photocatalytic degradation and removal of adsorbates in the presence of ZnO. 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subjects | 3D nanostructures atomic layer deposition Gold nanoscale gaps Nanostructures Photovoltaic cells prism holographic lithography Rough surfaces SERS substrates Substrates Surface treatment Three-dimensional displays Zinc oxide |
title | Fabrication of Au-Decorated 3D ZnO Nanostructures as Recyclable SERS Substrates |
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