Formation of SnOx nanoparticles at the AIDCN/ITO interface in organic cross-point memory devices

The formation characteristics and the effect on electrical behavior of the nanoparticles caused by the interfacial redox reaction are investigated in single-layer organic memory devices with a structure of Al(aluminium)/2-amino-4,5-dicyanoimidazole (AIDCN)/indium tin oxide (ITO). It is demonstrated...

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Hauptverfasser: Yun Li, Yedan Sun, Danfeng Qiu, Jianmin Zhu, Lijia Pan, Lin Pu, Yi Shi
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Yedan Sun
Danfeng Qiu
Jianmin Zhu
Lijia Pan
Lin Pu
Yi Shi
description The formation characteristics and the effect on electrical behavior of the nanoparticles caused by the interfacial redox reaction are investigated in single-layer organic memory devices with a structure of Al(aluminium)/2-amino-4,5-dicyanoimidazole (AIDCN)/indium tin oxide (ITO). It is demonstrated that the AIDCN/ITO interface is crucial for the electrically switching behavior, where SnOx nanoparticles are spontaneously formed by the chemical reaction between the tin oxide in ITO and the imine in AIDCN molecule. Moreover, an organic cross-point memory device with a metallic mid-layer was fabricated. I-V measurement presented an on-off ratio as high as 10 8 -10 11 .
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subjects Aluminum
Electric variables measurement
Electrodes
Glass
Indium tin oxide
Nanoparticles
Organic chemicals
Organic materials
Solid state circuits
Substrates
title Formation of SnOx nanoparticles at the AIDCN/ITO interface in organic cross-point memory devices
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