Exceptionally High Hc } Values in Alloyed Bulk Samples of Nb }Sn

Nb{}_{\text{3}}Sn is the original high-field superconductor but understanding its optimization in wire forms, which are always inhomogeneous, is compromised by a lack of basic understanding of its true property variations when it is alloyed with H c {}_{\text{2}} enhancing additions (e.g., Hf, Ta, T...

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Veröffentlicht in:IEEE transactions on applied superconductivity 2025-08, Vol.35 (5), p.1-6
Hauptverfasser: Mandal, Manish, Tarantini, Chiara, Starch, William L., Lee, Peter J., Larbalestier, David C.
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Tarantini, Chiara
Starch, William L.
Lee, Peter J.
Larbalestier, David C.
description Nb{}_{\text{3}}Sn is the original high-field superconductor but understanding its optimization in wire forms, which are always inhomogeneous, is compromised by a lack of basic understanding of its true property variations when it is alloyed with H c {}_{\text{2}} enhancing additions (e.g., Hf, Ta, Ti, Zr). Since improving the high-field performance of Nb{}_{\text{3}}Sn is important for many future applications in high energy physics, fusion, and medicine, we are studyingbulk binary and alloyed samples fabricated by ball milling itsconstituent powders and reacting them in a Hot Isostatic Press at pressures up to 2000 bar and temperatures up to 1800  °C. Remarkably, we found that these bulk samples, reacted to produce the A15 phase at temperatures between 1200 and 1800 °C, show minority traces of H c {}_{\text{2}} (0 K), evaluated with a 99% criterion, that reach almost 40 T, more than 27% higher than the best value previously reported for Nb{}_{\text{3}}Sn. These results are both scientifically interesting but potentially of great practical importance if they can be exploited for improving the high-field properties of Nb{}_{\text{3}}Sn wires. One caution is that these samples do not have added Cu as wires do and that the high H c {}_{{2}} reactions were all done at well above 1000 °C.
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Since improving the high-field performance of Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn is important for many future applications in high energy physics, fusion, and medicine, we are studyingbulk binary and alloyed samples fabricated by ball milling itsconstituent powders and reacting them in a Hot Isostatic Press at pressures up to 2000 bar and temperatures up to 1800  °C. Remarkably, we found that these bulk samples, reacted to produce the A15 phase at temperatures between 1200 and 1800 °C, show minority traces of H c <inline-formula><tex-math notation="LaTeX">{}_{\text{2}}</tex-math></inline-formula> (0 K), evaluated with a 99% criterion, that reach almost 40 T, more than 27% higher than the best value previously reported for Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn. These results are both scientifically interesting but potentially of great practical importance if they can be exploited for improving the high-field properties of Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn wires. One caution is that these samples do not have added Cu as wires do and that the high H c <inline-formula><tex-math notation="LaTeX">{}_{{2}}</tex-math></inline-formula> reactions were all done at well above 1000 °C.]]></description><subject>Alloying</subject><subject>Doping</subject><subject><![CDATA[H<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _c</tex-math> </inline-formula> </named-content><named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> {}_{\text{2}}</tex-math> </inline-formula> </named-content>]]></subject><subject>Hafnium</subject><subject>Heat treatment</subject><subject>Hip</subject><subject><![CDATA[Nb<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> {}_{\text{3}}</tex-math> </inline-formula> </named-content>Sn]]></subject><subject>Niobium-tin</subject><subject>Powders</subject><subject>Superconducting magnets</subject><subject>Temperature dependence</subject><subject>upper critical field</subject><subject>Wire</subject><issn>1051-8223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNqFybsOgjAUgOEOmoiXBzBxOC8AnrYQYBOJhskF4koqFq2WS6gkMvDuOrg7_cn3E7Km6FCK4TaL0thhyFyHexjyIJgQi6JH7YAxPiNzYx6I1A1czyK7w7uQ7Us1tdB6gETd7pAUMMJZ6F4aUDVEWjeDvMK-109IRdXqrzclnC4wpvWSTEuhjVz9uiCb4yGLE1tJKfO2U5Xohpyi79OQM_5nfwD16Tby</recordid><startdate>202508</startdate><enddate>202508</enddate><creator>Mandal, Manish</creator><creator>Tarantini, Chiara</creator><creator>Starch, William L.</creator><creator>Lee, Peter J.</creator><creator>Larbalestier, David C.</creator><general>IEEE</general><scope>97E</scope><scope>RIA</scope><scope>RIE</scope><orcidid>https://orcid.org/0000-0001-7098-7208</orcidid><orcidid>https://orcid.org/0000-0002-8849-8995</orcidid><orcidid>https://orcid.org/0009-0001-7587-5472</orcidid><orcidid>https://orcid.org/0000-0002-0551-5762</orcidid><orcidid>https://orcid.org/0000-0002-3314-5906</orcidid></search><sort><creationdate>202508</creationdate><title>Exceptionally High Hc } Values in Alloyed Bulk Samples of Nb }Sn</title><author>Mandal, Manish ; 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Since improving the high-field performance of Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn is important for many future applications in high energy physics, fusion, and medicine, we are studyingbulk binary and alloyed samples fabricated by ball milling itsconstituent powders and reacting them in a Hot Isostatic Press at pressures up to 2000 bar and temperatures up to 1800  °C. Remarkably, we found that these bulk samples, reacted to produce the A15 phase at temperatures between 1200 and 1800 °C, show minority traces of H c <inline-formula><tex-math notation="LaTeX">{}_{\text{2}}</tex-math></inline-formula> (0 K), evaluated with a 99% criterion, that reach almost 40 T, more than 27% higher than the best value previously reported for Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn. These results are both scientifically interesting but potentially of great practical importance if they can be exploited for improving the high-field properties of Nb<inline-formula><tex-math notation="LaTeX">{}_{\text{3}}</tex-math></inline-formula>Sn wires. One caution is that these samples do not have added Cu as wires do and that the high H c <inline-formula><tex-math notation="LaTeX">{}_{{2}}</tex-math></inline-formula> reactions were all done at well above 1000 °C.]]></abstract><pub>IEEE</pub><doi>10.1109/TASC.2024.3509388</doi><orcidid>https://orcid.org/0000-0001-7098-7208</orcidid><orcidid>https://orcid.org/0000-0002-8849-8995</orcidid><orcidid>https://orcid.org/0009-0001-7587-5472</orcidid><orcidid>https://orcid.org/0000-0002-0551-5762</orcidid><orcidid>https://orcid.org/0000-0002-3314-5906</orcidid></addata></record>
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subjects Alloying
Doping
H<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _c</tex-math> </inline-formula> </named-content><named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> {}_{\text{2}}</tex-math> </inline-formula> </named-content>
Hafnium
Heat treatment
Hip
Nb<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> {}_{\text{3}}</tex-math> </inline-formula> </named-content>Sn
Niobium-tin
Powders
Superconducting magnets
Temperature dependence
upper critical field
Wire
title Exceptionally High Hc } Values in Alloyed Bulk Samples of Nb }Sn
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